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Facile one-step solvothermal synthesis of a luminescent europium metal-organic framework for rapid and selective sensing of uranyl ions

  • Linnan Li
  • Sensen Shen
  • Jie Su
  • Wanpeng Ai
  • Yu Bai
  • Huwei LiuEmail author
Research Paper
  • 59 Downloads
Part of the following topical collections:
  1. New Insights into Analytical Science in China

Abstract

A simple, cost-effective, and portable uranium sensory material with adequate selectivity is increasingly urgent and would be of great importance in environmental monitoring of radionuclides. Herein, we report a novel luminescent europium metal-organic framework (Eu-MOF) with plenty of Lewis basic sites for binding uranyl ions (UO22+), the most common form of uranium in solution, through a facile one-step solvothermal synthetic route. The mesoporous structure consists of europium nodes and flexible nitrogen-containing ligands with a 29.2 × 20.5 Å2 channel along the c-axis. Furthermore, the obtained material displays characteristic fluorescence of trivalent Eu3+ and could be applied as a turn-off sensory probe targeting UO22+ in solution. Differential fluorescent quenching occurred upon a series of potential interfering ions compared to UO22+ and the detection limit as low as 0.9 μM was achieved with a rapid response.

Graphical abstract

Keywords

Metal-organic framework Europium Luminescent sensing Uranyl ions 

Notes

Funding information

This work was financially supported by the Collaboration Program of Institute of Materials, China Academy of Engineering Physics, the National Natural Science Foundation of China (Grant numbers, 21775008), and the Shanghai Sailing Program (19YF1448800).

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

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ESM 1 (PDF 2664 kb)
216_2019_1875_MOESM2_ESM.pdf (338 kb)
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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, Institute of Analytical Chemistry, College of Chemistry and Molecular EngineeringPeking UniversityBeijingChina
  2. 2.The MOE Key Laboratory for Standardization of Chinese Medicines, The SATCM Key Laboratory for New Resources and Quality Evaluation of Chinese Medicines, Institute of Chinese Materia MedicaShanghai University of Traditional Chinese MedicineShanghaiChina
  3. 3.Analytical Instrumentation CenterPeking UniversityBeijingChina

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