Laser pulse alloying the surface of Ti-5.5Al-2Zr-1Mo-1V by boron carbide particles

  • A. I. GorunovEmail author


The laser alloying of the Ti-5.5Al-2Zr-1Mo-1V near alpha-titanium alloy surface by boron carbide particles was performed. The pulse laser radiation is melting the surface of specimen a near alpha-titanium alloy, while simultaneously feeding BC powder to alloying zone. The powerful impulse laser effect obtained microexplosion above surface of the sample. The powerful explosive acoustic wave above the sample surface accelerates particles boron carbide. The surface of titanium alloy where charged by carbide particles. The laser alloying to obtained partial melting of the powder particles of boron carbide and dilution with the molten bath on the surface of titanium alloy. The new phases of TiC, TiB, and TiB2 dendrites-shaped and fine-dispersed needles were formed. The microhardness and coefficient of friction of the alloyed surface of a titanium alloy was increased into 2 and 1.5 times respectively.


Laser alloying Titanium alloy Tribological tests Boron carbide Microstructure 


Funding information

The authors are grateful to the Ministry of Education of the Russian Federation for supported research projects No. 9.3236.2017/4.6, grant of the President of the Russian Federation MK-3745.2019.8 and Russian Science Foundation 19-79-00039.


  1. 1.
    Gurrappa I, Gogia AK (2001) High performance coatings for titanium alloys to protect against oxidation. Surf Coat Technol 139:216–221CrossRefGoogle Scholar
  2. 2.
    Lei TC, Ouyang JH, Pei YT, Zhou Y (1995) Microstructure and wear-resistance of laser clad tic particle-reinforced coating. Mater Sci Technol 11:520–525CrossRefGoogle Scholar
  3. 3.
    Budinski KG (1991) Tribological properties of titanium-alloys. Wear 151:203–217CrossRefGoogle Scholar
  4. 4.
    Luo Y, Ge S, Jin Z, Fisher J, Mischler S (2009) Effect of surface modification on surface properties and tribological behaviours of titanium alloys. Proc Inst Mech Eng J J Eng Tribol 223:605–605Google Scholar
  5. 5.
    Feng S-r, Tang H-b, Zhang S-q, Wang H-m (2012) Microstructureand wear resistance of laser clad TiB–TiC/TiNi–Ti2Ni intermetallic coating ontitanium alloy. Trans Nonferrous Metals Soc China 22(7):1667–1673CrossRefGoogle Scholar
  6. 6.
    Fotovvati B, Namdari N, Dehghanghadikolaei A (2019) On coating techniques for surface protection: a review. J Manuf Mater Process 3(1):28Google Scholar
  7. 7.
    Zhang K-m, Zou J-x, Li J, Yu Z-s, Wang H-p (2012) Synthesis ofY2O3 particle enhanced Ni/TiC composite on TC4 Ti alloy by laser cladding. Trans Nonferrous Metals Soc China 22(8):1817–1823CrossRefGoogle Scholar
  8. 8.
    Zhang K-m, Zou J-x, Li J, Yu Z-s, Wang H-p (2010) Surface modifi-cation of TC4 Ti alloy by laser cladding with TiC + Ti powders. Trans Nonferrous Metals Soc China 20:2192–2197CrossRefGoogle Scholar
  9. 9.
    Sharma S (2012) Wear study of Ni-WC composite coating modified with CeO2. Int J Adv Manuf Technol 61(9–12):889–900CrossRefGoogle Scholar
  10. 10.
    Wu WL (2010) Dissolution precipitation mechanism of TiC/Ti composite layer pro-duced by laser cladding. Mater Sci Technol 26:367–370CrossRefGoogle Scholar
  11. 11.
    Tian YS (2010) Growth mechanism of the tubular TiB crystals in situ formed in the coatings laser-borided on Ti–6Al–4V alloy. Mater Lett 64:2483–2486CrossRefGoogle Scholar
  12. 12.
    Cai C, Radoslaw C, Zhang J, Yan Q, Wen S, Song B, Shi Y (2019) In-situ preparation and formation of TiB/Ti-6Al-4V nanocomposite via laser additive manufacturing: microstructure evolution and tribological behavior. Powder Technol 342:73–84CrossRefGoogle Scholar
  13. 13.
    Zhang C, Guo Z, Yang F, Wang H, Shao Y, Lu B (2018) In situ formation of low interstitials Ti-TiC composites by gas-solid reaction. J Alloys Compd 769:37–44CrossRefGoogle Scholar
  14. 14.
    Hou Q, Ma X, Lu R, Wang W, Wang P, Huang Z (2019) Microstructure and laser irradiation characteristics of TiC-free and TiC doped tungsten-based coatings prepared by supersonic atmospheric plasma spraying. Surf Coat Technol 358:796–805CrossRefGoogle Scholar
  15. 15.
    Diao Y, Zhang K (2015) Microstructure and corrosion resistance of TC2 Ti alloy by laser cladding with Ti/TiC/TiB2 powders. Appl Surf Sci 352:163–168CrossRefGoogle Scholar
  16. 16.
    Tijo D, Masanta M (2019) Effect of Ti/B4C ratio on the microstructure and mechanical characteristics of TIG cladded TiC-TiB2 coating on Ti-6Al-4V alloy. J Mater Process Technol 266:184–197CrossRefGoogle Scholar
  17. 17.
    He X, Song RG, Kong DJ (2019) Effects of TiC on the microstructure and properties of TiC/TiAl composite coating prepared by laser cladding. Opt Laser Technol 112:339–348CrossRefGoogle Scholar
  18. 18.
    Attar H, Löber L, Funk A, Calin M, Zhang LC, Prashanth KG, Scudino S, Zhang YS, Eckert J (2015) Mechanical behavior of porous commercially pure Ti and Ti–TiB composite materials manufactured by selective laser melting. Mater Sci Eng A 625:350–356CrossRefGoogle Scholar
  19. 19.
    Yang C, Zhang J, Daia N, Qin P, Attar H, Zhang L-C (2017) Corrosion behaviour of selective laser melted ti-tib biocomposite in simulated body fluid. Electrochim Acta 232:89–97CrossRefGoogle Scholar
  20. 20.
    Hu Y, Cong W, Wang X, Li Y, Ning F, Wang H (2018) Laser deposition-additive manufacturing of TiB-Ti composites with novel three-dimensional quasi-continuous network microstructure: effects on strengthening and toughening. Compos Part B 133:91–100CrossRefGoogle Scholar
  21. 21.
    Xia M, Liu A, Hou Z, Li N, Chen Z, Ding H (2017) Microstructure growth behavior and its evolution mechanism during laser additive manufacture of in-situ reinforced (TiB-TiC)/Ti composite. J Alloys Compd 728:436–444CrossRefGoogle Scholar
  22. 22.
    Attar H, Ehtemam-Haghighi S, Kent D, Okulov IV, Wendrock H, Bӧnisch M, Volegov AS, Calin M, Eckert J, Dargusch MS (2017) Nanoindentation and wear properties of Ti and Ti-TiB composite materials produced by selective laser melting. Mater Sci Eng A 688:20–26CrossRefGoogle Scholar
  23. 23.
    Zeng X, Yamaguchi T, Nishio K (2016) Characteristics of Ti (C,N)/TiB composite layer on Ti–6Al–4V alloy produced by laser surface melting. Opt Laser Technol 80:84–91CrossRefGoogle Scholar
  24. 24.
    Wang H, Sun S, Wang D, Tu G (2012) Characterization of the structure of TiB2/TiC composites prepared via mechanical alloying and subsequent pressure less sintering. Powder Technol 217:340–346CrossRefGoogle Scholar
  25. 25.
    Feng Y, Feng K, Yao C, Li Z, Sun J (2018) Microstructure and properties of in-situ synthesized (Ti3Al + TiB)/Ti composites by laser cladding. Mater Des 157:258–272CrossRefGoogle Scholar
  26. 26.
    Gorunov AI (2019) Laser alloying of surface of Ti-5.5Al-2Zr-1Mo-1 V titanium near-α-alloy prepared via melted by pulsed laser radiation TiC particles. Lasers Manuf Mater Process 6:26–40CrossRefGoogle Scholar
  27. 27.
    Wang L, Wang X, Zhang L-C, Lu W (2015) Ultrafine processing of (TiB-TiC)/TC18 composites processed by ECAP via Bc route. Mater Sci Eng A 645:99–108CrossRefGoogle Scholar
  28. 28.
    Guo W, Sun R, Song B, Zhu Y, Li F, Che Z, Li B, Guo C, Liu L, Peng P (2018) Laser shock peening of laser additive manufactured Ti6Al4V titanium alloy. Surf Coat Technol 349:503–510CrossRefGoogle Scholar
  29. 29.
    Huang S, Sheng J, Li J, Agyenim-Boateng E (2019) Effect of laser peening on friction and wear behavior of medical Ti6Al4V. Alloy Optics Laser Technol 109:263–269CrossRefGoogle Scholar
  30. 30.
    Salehi D, Brandt M (2006) Melt pool temperature control using LabVIEW in Nd: YAG laser blown powder cladding process. Int J Adv Manuf Technol 29(3–4):273–278CrossRefGoogle Scholar
  31. 31.
    Fotovvati B, Wayne SF, Lewis G, Asadi E (2018) A review on laser welding of metals. Adv Mater Sci Eng 2018:1–18. CrossRefGoogle Scholar
  32. 32.
    Das M, Balla VK, Basu D, Bose S, Bandyopadhyay A (2010) Laser processing of SiC-particle-reinforced coating on titanium. Scr Mater 63(4):438–441CrossRefGoogle Scholar
  33. 33.
    Tian YS, Zhang QY, Wang DY (2009) Study on the microstructures and propertiesof the boride layers laser fabricated on Ti–6Al–4V alloy. J Mater Process Technol 209(6):2887–2891CrossRefGoogle Scholar
  34. 34.
    Balyanov A, Kutnyakova J, Amirkhanova NA, Stolyarov VV, Valiev RZ, Liao XZ, Zhao YH, Jiang YB, Xu HF, Lowe TC, Zhu YT (2004) Corrosion resistance of ultra fine-grained Ti. Scr Mater 51:225–229CrossRefGoogle Scholar
  35. 35.
    Konitzer DG, Loretto MH (1989) Microstructural assessment of Ti6Al4V-TiC metal-matrix composite. Acta Metall 2(37):397–406CrossRefGoogle Scholar
  36. 36.
    Loretto MH, Konitzer DG (1990) The effect of matrix reinforcement reaction on fracture in Ti-6AI-4V-base composites. Metall Trans A 21:1579–1587CrossRefGoogle Scholar
  37. 37.
    Storms EK (1967) Refractory materials. In: Storms EK (ed) The refractory carbides, vol 2. Academic Press, Cambridge MA, p 285CrossRefGoogle Scholar
  38. 38.
    Basu et al (2006) Processing and properties of monolithic TiB2 based materials. Int Mater Rev 51:352CrossRefGoogle Scholar
  39. 39.
    Murray JL (1986) The B-Ti (Boron-Titanium) System. Bull Alloy Phase Diagr 7(6):550–555CrossRefGoogle Scholar
  40. 40.
    Majumdar JD, Li L (2010) Development of titanium boride (TiB) dispersed titanium (Ti) matrix composite by direct laser cladding. Mater Lett 64:1010–1012CrossRefGoogle Scholar

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© Springer-Verlag London Ltd., part of Springer Nature 2019

Authors and Affiliations

  1. 1.Kazan National Research Technical University named after Tupolev A.N.–KAIKazanRussia

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