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Accurate and Sensitive Determination Method for Procymidone and Chlorflurenol in Municipal Wastewater, Medical Wastewater and Irrigation Canal Water by GC–MS After Vortex Assisted Switchable Solvent Liquid Phase Microextraction

  • Fatih Kapukıran
  • Merve Fırat
  • Dotse Selali Chormey
  • Sezgin BakırdereEmail author
  • Nizamettin ÖzdoğanEmail author
Article

Abstract

In this study, the detection power of a gas chromatography mass spectrometer (GC–MS) for procymidone and chlorflurenol was significantly enhanced using switchable solvent liquid phase microextraction (SS-LPME) as a preconcentration tool. This was achieved by a comprehensive optimization of significant parameters to the SS-LPME method such as switchable solvent amount, concentration and amount of sodium hydroxide, pH effect and mixing effect. The optimum experimental conditions obtained were used to determine analytical figures of merit for the analytes. The limits of detection obtained were 0.44 and 2.9 ng/mL for procymidone and chlorflurenol, respectively. The optimum method was applied to water sampled from an irrigation canal and two wastewater samples. The samples were spiked at two concentrations and the percent recovery results obtained ranged between 86 and 115% for both analytes. The recovery results together with the low standard deviations recorded validated the method as accurate and precise.

Keywords

Pesticide Switchable solvent GC–MS Procymidone Chlorflurenol 

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • Fatih Kapukıran
    • 1
  • Merve Fırat
    • 2
  • Dotse Selali Chormey
    • 2
  • Sezgin Bakırdere
    • 2
    Email author
  • Nizamettin Özdoğan
    • 1
    Email author
  1. 1.Environmental Engineer DepartmentInstitute of Science, Bülent Ecevit UniversityZonguldakTurkey
  2. 2.Faculty of Art and Science, Chemistry DepartmentYıldız Technical UniversityİstanbulTurkey

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