Interceram - International Ceramic Review

, Volume 66, Issue 5, pp 166–170 | Cite as

Effect of Two Different Types of Capping Agents on the Synthesis and Characterisation of Zinc Oxide

  • S. MukherjeeEmail author
  • S. Das Nath
  • P. Bhadra
High-Performance Ceramics


Zinc oxide was functionalised by a solid state process using two capping agents: PEG (polymer) and CTAB (surfactant). The phases that formed were identified by XRD and crystallite size was determined using Scherer’s formula. With PEG, the crystallite size was found to vary between 20 and 50 nm. Using CTAB, the range was from about 38 to 30 nm. The morphology of the synthesised samples was identified using FESEM. Cube-like features were obtained using PEG as surfactant whereas rod-like morphology was formed with CTAB. M-O coordination and symmetric-asymmetric bonding information was obtained from FTIR analysis of both the PEG- and CTAB-assisted ZnO. Band gap for both cases was evaluated using Tauc plots from UV-VIS spectra. The band gap was found to vary with PEG and CTAB concentration increases in reversed manner, and was noted to be close in value to semiconductor materials.


ZnO morphology symmetric-asymmetric bonding band gap 


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  1. [1]
    Radzimska-Kołodziejczak, A., Jesionowski, T.: Zinc oxide-from synthesis to application: A review. Materials 7 (2014) 2833–2881CrossRefGoogle Scholar
  2. [2]
    Yang Jinghai, Wang Rui, Yang Lili, Lang Jihui, Wei Maobin, Gao Ming, Liu Xiaoyan, Cao Jian, Li Xue, Yang Nannan.: Tunable deep-level emission in ZnO nanoparticles via yttrium doping. J. Alloy. Compd. 509 (2011) 3606–3612CrossRefGoogle Scholar
  3. [3]
    Gupta K. Manoj, Sinha Nidhi, Kumar Binay.: Dielectric studies and band gap tuning of ferroelectric Cr-doped ZnO nanorods. J. Appl. Phys. 112 (2012) 014303–1–014303–4CrossRefGoogle Scholar
  4. [4]
    Wang Baiqi, Iqbal Javed, Shan Xudong, Huang Guowei, Fu Honggang, Yu Ronghai, Yu Dapeng: Effects of Cr-doping on the photoluminescence and ferromagnetism at room temperature in ZnO nanomaterials prepared by soft chemistry route. Mat. Chem. Phy. 113 (2009) 103–106CrossRefGoogle Scholar
  5. [5]
    Zheng, J.H., Son, L.J., Jiang, Q., Lian, S.J.: Enhanced UV emission of Y-doped ZnO Nanoparticles. Appl. Surf. Sci. 258 (2012) 6735–6838CrossRefGoogle Scholar
  6. [6]
    Anandan, S., Muthukumaran, S.: Influence of Yttrium on optical, structural and photoluminescence properties of ZnO nanopowders by sol-gel method. Optical Mat. 35 (2013) 2241–2249CrossRefGoogle Scholar
  7. [7]
    Sanoop, P.K, Anas, S., Ananthakumar, S., Gunasekar, V., Saravanan, R., Ponnusami, V.: Synthesis of yttrium doped nanocrystalline ZnO and its photocatalytic activity in methylene blue degradation. Arab. J. Chem. 9 (2016) 1618–1626CrossRefGoogle Scholar
  8. [8]
    Desoky-El, M.M., Ali, M.A., Afifi, G., Imam, H., Assiri-Al, M.S.: Effects of annealing temperatures on the structural and dielectric properties of ZnO nanoparticles. Silicon. (2016). DOI: 10.1007/s12633-016-9445-5CrossRefGoogle Scholar
  9. [9]
    Adhyapak V. Parag, Meshram P. Satish, Tomar Vijaykumar, Amalnerkar P. Dinesh, Mulla S. Imtiaz: Effect of preparation parameters on the morphologically induced photocatalytic activities of hierarchical zinc oxide nanostructures. Ceram. Int. 39 (2013) 7367–7378CrossRefGoogle Scholar
  10. [10]
    Sharma K. Sanjeev, Kim Young Deuk: Microstructure and optical properties of yttrium-doped zinc oxide (YZO) nanobolts synthesized by hydrothermal method. J. Mater. Sci. Tech. 32 (2016) [1] 12–16CrossRefGoogle Scholar
  11. [11]
    Hassan Mehedi, M., Ahmed S. Arham, Chaman, M., Khan Wasi, Naqvi, A.H., Azam Ameer: Structural and frequency dependent dielectric properties of Fe3+ doped ZnO Nanoparticles. Mater. Res. Bull. 47 (2012) 3952–3958CrossRefGoogle Scholar
  12. [12]
    Kumar Siva Surabhi, Venkateswarlu Putcha, Rao Ranga Vanka, Rao Nageswara Gollapalli: Synthesis, characterization and optical properties of zinc oxide nanoparticles. Int. Nano Letters 3 (2013) 1–6CrossRefGoogle Scholar

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© Springer Fachmedien Wiesbaden GmbH, part of Springer Nature 2017

Authors and Affiliations

  1. 1.Amity School of Engineering & TechnologyAmity University KolkataKolkataIndia
  2. 2.Department of Metallurgical & Materials EngineeringJadavpur UniversityKolkataIndia

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