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Carbonates and Evaporites

, Volume 12, Issue 2, pp 296–324 | Cite as

The geological history of Messinian (upper miocene) evaporites in the Central Jordan Valley (Israel) and how strontium and sulfur isotopes relate to their origin

  • M. Raab
  • G. M. Friedman
  • B. Spiro
  • A. Starinsky
  • I. Zak
Article
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Abstract

Evaporites, comprising gypsum, anhydrite, halite and dolomite are described from the Messinian Bira Formation outcrops and from two boreholes (Newe Ur-2 and Zemah-1) in the Central Jordan Valley, Israel. Strontium and sulfur isotopic compositions of the evaporite minerals, and their Sr/Ca and Br/Cl ratios are used to interpret their enviromments of deposition and processes of formation and diagenesis. The brines from which the evaporites precipitated originated from seawater. The processes caused by mixing of surface water, seawater and subsurface brines, resulted in dolomitization and also sulfur reduction. The surface water and subsurface brines reacted with the rocks they drained, including Cretaceous and Eocene carbonates and Neogene basalts. The gypsum deposits in the Central Jordan Valley are interpreted to have formed as a result of evaporation of the magnesium-rich Lake Bira water which became oversaturated with respect to calcite and gypsum. The gypsum was deposited in stratified, relatively closed basins, where a partial reduction of the sulfur resulted in high δ34S of the precipitated gypsum. Gypsum and early diagenetic dolomite formed from the same water bodies. The Bira evaporites in Newe Ur-2 borehole, precipitated from mixtures of sea- and fresh waters with basaltic contribution. The samples from the Lower Gabbro and Halite Unit in the Zemah-1 borehole were deposited from evaporated seawater, which leached basaltic rocks, in closed basins; the Middle Halite Unit formed from seawater, whiles the brines that deposited the Upper Halite Unit leached also basalt rocks.

Keywords

Gypsum Halite Anhydrite Evaporite 86Sr 
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References

  1. BERRY, L.G., 1974, Selected powder diffraction data for minerals. Jt. Comm. Powder Diffr. Stand., Swarthmore, Pennsylvania, 833 p.Google Scholar
  2. BEYTH, M., 1966, A survey of gypsum deposits in the Gesher area: Geological Survey of Israel, Jerusalem. Unpublished Report MP/156/66, 7 p. (in Hebrew).Google Scholar
  3. BEYTH, M. and WEISSBROD, T., 1965, A survey for the development of the gypsum quarry at Gesher: Geological Survey of Israel, Jerusalem. Unpublished Report MP/160/65, 7 p. (in Hebrew).Google Scholar
  4. BRAUN, D., 1992, The geology of the Afiqim region. Unpublished M. Sc. Thesis, The Hebrew University Jerusalem, 93 p. (in Hebrew).Google Scholar
  5. BURKE, R.E., DENISON, R.E., HETHERINGTON, R.B., KOEPNICK, H.F., NELSON H.F., and OTTO, J.B., 1982, Variation of seawater87Sr/86Sr throughout Phanerozoic time:Geology, v. 10, p. 516–519.CrossRefGoogle Scholar
  6. COLEMAN, M.L. and MOORE, M.P., 1978, Direct reduction of sulfates to sulfur dioxide for isotopic analysis:Analytical Chemistry, v. 50, p. 1594–1595.CrossRefGoogle Scholar
  7. CLAYPOOL, G.E., HOLSER, W.T., KAPLAN, I.R., SAKAI, H., and ZAK, I., 1980,Chemical Geology, v. 28, p. 199–260.CrossRefGoogle Scholar
  8. DEPAOLO, D.J. and INGRAM, B.L., 1985, High-resolution stratigraphy with strontium isotopes:Science, v. 227, p. 938–941.CrossRefGoogle Scholar
  9. FARRELL, J.W., CLEMENS, S.C., and GROMET, L.P., 1995, Improved chronostratigraphic reference curve of late Neogene seawater87Sr/86Sr:Geology, v. 23, p. 403–406.CrossRefGoogle Scholar
  10. FREUND, R., 1978, Judean Hills and Galilee, regional synthesis of sedimentary basins: 10th International Congress of Sedimentology, Jerusalem, Israel, v. I, p. 1–31.Google Scholar
  11. FRIEDMAN, G.M., 1995, Diverse origin of modern dolomites in the Levant:Carbonates and Evaporites, v. 10, p. 65–78.CrossRefGoogle Scholar
  12. FUGE, R., 1974, Bromine abundance in common igneous rock types.In Wedepohl, K.J., (Ed.), Handbook of Geochemistry. Springer Verlag, Berlin, v. II-4, pt. 35E, p. 1–5.Google Scholar
  13. HAQ, B.A., HARDENBAL, J., and VAIL, R., 1987, Chronology of fluctuating sea levels since the Triassic:Science, v. 255, p. 1156–1166.CrossRefGoogle Scholar
  14. HEIMANN, A., 1990, The development of the Dead Sea rift and its margins in Northern Israel during the Pliocene and the Pleistocene. Geological Survey of Israel, Jerusalem, Report GSI/28/90, 83 p. (in Hebrew, English abstract).Google Scholar
  15. HERUT, B., SPIRO, B., STARINSKY, A., and KATZ, A., 1995, Sources of sulfur in rainwater as indicated by isotopic δ34S data and chemical compositions, Israel:Atmospheric Environments, v. 29, p. 851–857.CrossRefGoogle Scholar
  16. HOLSER, W.T., 1966, Bromide geochemistry of salt rocks.In Rau, J.L., Second symposium on salt: Cleveland, Ohio:Northern Ohio Geological Society, v. 2, p. 248–275.Google Scholar
  17. HOLSER, W.T., 1979, Trace elements and isotopes in evaporates.In Marine Minerals:Mineralogical Society of America, v. 6, p. 295–346.Google Scholar
  18. HOROWITZ, A., 1983, Palynostratigraphy of Zemah 1 borehole.In Marcus, E., Slager, Y., Ben-Zaken, S., and Indik, I.Y., 1984, Zemah-1, Geological Completion Report: Oil Exploration (Investments), Tel Aviv. Unpublished Report 84/11, p. 38–46.Google Scholar
  19. KOHN, B. P., SCHULMAN M., and AHARON, P., 1977, The origin of the magnetites in the Menachemiya (Sic!) gypsum deposit. Israel Geological Society, Annual Meeting, Zikhron Ya'acov, Abstracts, p. 26–27.Google Scholar
  20. KUSHNIR, J., 1982, The partitioning of seawater cations during the transformation of gypsum to anhydrite:Geochimica et Cosmochimica Acta, v. 46, p. 433–446.CrossRefGoogle Scholar
  21. MARCUS, E. and SLAGER, J., 1985, The sedimentary-magmatic sequence of the Zemah 1 well (Jordan-Dead Sea Rift, Israel) and its Emplacement in Time and Space:Israel Journal of Earth Sciences, v. 34, p. 1–10.Google Scholar
  22. MARCUS, E., SLAGER, Y., BEN-ZAKEN, S., and INDIK, I. Y., 1984, Zemah-1, Geological Completion Report: Oil Explor-ation (Investments), Tel Aviv. Unpublished Report 84/11, 108 p.Google Scholar
  23. MCCLUNE, W.F., MAGUIRE, T.M., MROSE, M.E., POST, BENJAMIN, WEISSMANN, SIGMUND, and MCMURDIE, H.F., 1983, Group data book: mineral powder diffraction file. Int. Cent. Diffr. Data, Joint Comm. Powder Diffr. Stand., Swarthmore, Pennsylvania, 1005 p.Google Scholar
  24. MICHELSON, H., 1972, The hydrogeology of the Southern Golan Heights: Water Planning of Israel (TAHAL). Unpublished Report HR/72/037, 89 p. (in Hebrew).Google Scholar
  25. NIELSEN, H., 1979, Sulfur isotopes.In Jaeger, E. and Hunziker, J.C., Lectures in isotope geology. Springer Verlag, Berlin., p. 283–312.CrossRefGoogle Scholar
  26. NISSENBAUM, A., 1969, Studies in the geochemistry of the Jordan River-Dead Sea system. Unpublished Ph. D. Dissertation, University of California, Los Angeles, 284 p.Google Scholar
  27. NISSENBAUM, A., NATHAN, Y., and SASS, E., 1977, Contact metamorphism in a Neogene evaporitic sequence of the central Jordan Valley — northern Israel:Mineralogical Magazine, v. 41, p. 233–238.CrossRefGoogle Scholar
  28. RAAB, M., 1996, The origin of the evaporites in the Jordan-Dead Sea Valley in view of the evolution of brines and evaporites during seawater evaporation. Unpublished Ph. D. thesis, The Hebrew University Jerusalem, 114 p. (in Hebrew, English Abstract).Google Scholar
  29. RAAB, M. and SPIRO, B., 1991, Sulfur isotopic variations during seawater evaporation with fractional crystallisation:Chemical Geology (Isotope Geosciences Section), v. 86, p. 323–333.CrossRefGoogle Scholar
  30. ROSENFELD, A., SEGEV, A., and HALBERSBERG, E., 1981, Ostracode species and paleosalinities of the Pliocene Bira and Gesher Formations (Northwestern Jordan Valley):Israel Journal of Earth Sciences, v. 30, p. 113–119.Google Scholar
  31. SANDLER, A., 1981, The geochemistry of groundwaters from basaltic aquifers in the Lower Galilee and the Golan. Geological Servey of Israel, Jerusalem, Report HYDRO/2/81, 91 p. (in Hebrew, English Abstract.)Google Scholar
  32. SANDLER, A., RAAB, M., and NATHAN, Y., 1989, Clay mineralogy of deeply buried Neogene sediments in the Jordan Rift Valley. Israel Geological Society, Annual Meeting, Ramot. Abstracts, p. 132.Google Scholar
  33. SASS, E. and BEIN, A., 1988, Dolomites and salinity: A comparative geochemical study:Society of Economic Paleontologists and Mineralogists, Special Publication 43, p. 223–233.Google Scholar
  34. SEGEV, A. and MOSHKOVITZ, S., 1985, A geological survey to locate gypsum in the Doshen area (Nahal Yissakhar). Geological Survey of Israel, Jerusalem, Unpublished Report GSI/17/85, 9 p. (in Hebrew).Google Scholar
  35. SEGEV, A. and WACHS, D., 1979, A geological-geophysical tentative survey to locate gypsum bodies in the Menahemya area. Geological Survey of Israel, Jerusalem, Unpublished Report MP/588/79, 12 p. (in Hebrew).Google Scholar
  36. SCHULMAN, N., 1959, The geology of the Central Jordan Valley:Bulletin of the Research Council of Israel, v. 8G, p. 63–90.Google Scholar
  37. SCHULMAN, N., 1962, The geology of the Central Jordan Valley. Unpublished Ph. D. Thesis, The Hebrew University, Jerusalem, 105 p. (in Hebrew, English Abstract).Google Scholar
  38. SHALIV, G., 1980, Newe Ur-2 borehole. Summary of findings: Water Planning of Israel (TAHAL), Unpublished Report 5 p. (in Hebrew).Google Scholar
  39. SHALIV, G., 1991, Stages in the tectonic and volcanic history of the Neogene basin in the Lower Galilee and the Valleys. Geological Survey of Israel, Jerusalem, Report GSI/11/91, 94 p. (in Hebrew, English Abstract).Google Scholar
  40. SHALIV, G., HATZOR, Y., and MIMRAN, Y., 1988, Sedimentary, structural and morphological development of NE Samaria, Bet-She'an Valley and the Gilboa' margins in the Neogene-Quaternary. Israel Geological Society, Annual Meeting, 'En Boqeq. Abstracts, p. 102–103.Google Scholar
  41. SNEH, A., 1993, Stratigraphic position of marine Pliocene deposits in the lower Galilee and the Yizre'el Valley. Geological Survey of Israel, Current Research 8, p. 74–75.Google Scholar
  42. STARINSKY, A. and BIELSKY, M., 1981, The strontium isotopic composition of saline waters along the Dead Sea Rift. 7th European Colloquium of Geochronology and Cosmo-chronology, Jerusalem, Israel.Google Scholar
  43. STARINSKY, A., HEIMANN, A., and SHEMESH, O., 1987, The isotopic composition of strontium in snails living on basalts (Golan Heights) as an indicator to the origin of the shell. Golan Research Institute, Unpublished Final Report, 17 p. (in Hebrew)Google Scholar
  44. WAKSHAL, E., 1984, The isotopic composition of δ34S in the evaporites of Zemach 1 (Sic!) borehole and in saline waters within the Jordan Rift and the northern traversal valleys, Israel. Israel Geological Society, Annual Meeting, Arad. Abstracts, p. 100–101.Google Scholar
  45. WAKSHAL, E. and NIELSEN, H., 1982, Variations of δ34S (SO4), δ18O (H2O) and Cl/SO4 ratio in rainwater over northern Israel, from the Mediterranean Coast to the Jordan Rift Valley and Golan Heights:Earth and Planetary Sciences Letters, v. 61, p. 272–282.CrossRefGoogle Scholar

Copyright information

© Springer 1997

Authors and Affiliations

  • M. Raab
    • 1
  • G. M. Friedman
    • 2
    • 3
  • B. Spiro
    • 4
  • A. Starinsky
    • 5
  • I. Zak
    • 5
  1. 1.Geological Survey of IsraelJerusalemIsrael
  2. 2.Brooklyn College and Graduate School of the City University of New YorkBrooklyn
  3. 3.Rensselaer Center of Applied GeologyNortheastern Science Foundation affiliated with Brooklyn College of the City University of New YorkTroy
  4. 4.Isotope Geosciences LaboratoryBritish Natural Environment Research CouncilNottinghamUK
  5. 5.The Institute of Earth ScienceThe Hebrew University of JerusalemJerusalemIsrael

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