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Thermochemical studies for determination of the molar enthalpy of formation of aniline derivatives

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Abstract

The standard (p o=0.1 MPa) molar enthalpies of combustion atT=298.15 K were measured by static bomb combustion calorimetry for liquidN,N-diethylaniline,N,N-dimethyl-m-toluidine,N,N-dimethyl-p-toluidine, andN-ethyl-m-toluidine. Vaporization enthalpies forN,N-dimethyl-m-toluidine andN-ethyl-m-toluidine were determined by correlation gas chromatography. Derived standard molar values of δf H om (g) at 298.15 K forN,N-diethylaniline (62.1±7.6);N,N-dimethyl-m-toluidine (72.6±7.3),N,N-dimentyl-p-toluidine (68.9±7.4),N-ethyl-m-toluidine (30.5±3.8 kJ· mol−1) were obtained.

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Authors and Affiliations

  1. Centra de InvestigaÇÃo em Quimica, Department of Chemistry, Faculty of Science, University of Porto, P-4050, Porto, Portugal

    Manuel A. V. Ribeiro da Silva, Maria Dores M. C. Ribeiro da Silva, Maria Fatima B. M. Monteiro, Maria Luísa A. C. N. Gomes & Anjanette P. Smith

  2. Department of Chemistry, University of Missouri-St. Louis, 63121, St. Louis, Missouri

    James S. Chickos

  3. Department of Chemistry and Biochemistry, University of Maryland Baltimore County, 21228, Baltimore, Maryland

    Joel F. Liebman

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  1. Manuel A. V. Ribeiro da Silva
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  2. Maria Dores M. C. Ribeiro da Silva
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  3. Maria Fatima B. M. Monteiro
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  4. Maria Luísa A. C. N. Gomes
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  5. James S. Chickos
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  6. Anjanette P. Smith
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  7. Joel F. Liebman
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Ribeiro da Silva, M.A.V., Ribeiro da Silva, M.D.M.C., Monteiro, M.F.B.M. et al. Thermochemical studies for determination of the molar enthalpy of formation of aniline derivatives. Struct Chem 7, 367–373 (1996). https://doi.org/10.1007/BF02275163

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  • DOI: https://doi.org/10.1007/BF02275163

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