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Reaction Kinetics and Catalysis Letters

, Volume 17, Issue 3–4, pp 215–219 | Cite as

General equation for dissociative heterolytic reaction rates and corrections to the Brönsted relationship

  • E. S. Rudakov
Article

Abstract

A general equation is proposed for the rates of halide and H+ ion transfer. A relay-type participation of H2O in the transfer of H+ in aqueous solutions is substantiated.

Keywords

Physical Chemistry Aqueous Solution Catalysis Halide General Equation 

Abstract

Предложено общее уравнение для скоростей злементарных реакций цереноса заряженной группы: галоген-иона и H+. Получено доказательство эстафетного участия H2O при переносе H+ в водных растворах.

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References

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Copyright information

© Akadémiai Kiadó 1981

Authors and Affiliations

  • E. S. Rudakov
    • 1
  1. 1.Institute of Physical Organic and Coal ChemistryDonetskUSSR

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