Reaction Kinetics and Catalysis Letters

, Volume 17, Issue 3–4, pp 215–219 | Cite as

General equation for dissociative heterolytic reaction rates and corrections to the Brönsted relationship

  • E. S. Rudakov


A general equation is proposed for the rates of halide and H+ ion transfer. A relay-type participation of H2O in the transfer of H+ in aqueous solutions is substantiated.


Physical Chemistry Aqueous Solution Catalysis Halide General Equation 


Предложено общее уравнение для скоростей злементарных реакций цереноса заряженной группы: галоген-иона и H+. Получено доказательство эстафетного участия H2O при переносе H+ в водных растворах.


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  1. 1.
    J. N. Brönsted, K. J. Pedersen: J. Phys. Chem.,108, 185 (1924).Google Scholar
  2. 2.
    E. S. Rudakov, I. V. Kozhevnikov: Reactivity of Organic Substances,9, 1 (31), 165 Tartu, 1972.Google Scholar
  3. 3.
    E. S. Rudakov, I. V. Kozhevnikov, V. V. Zamashchikov: Usp. Khim.,43, 707 (1974).CrossRefGoogle Scholar
  4. 4.
    E. S. Rudakov: Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk,3, 152 (1980).Google Scholar
  5. 5.
    E. S. Rudakov: Dokl. Aiad. Nauk SSSR,212, 417 (1973).Google Scholar
  6. 6.
    E. S. Rudakov, V. V. Zamashchikov, S. L. Litvinenko: Reactivity of Organic Substances,15, 3 (55), 323, Tartu 1978.Google Scholar
  7. 7.
    R. Bell: The Proton in Chemistry. Mir, Moskva 1977.Google Scholar
  8. 8.
    E. S. Rudakov, V. L. Lobachev, A. F. Pryadko: React. Kinet. Catal. Lett.,17, 221 (1981).CrossRefGoogle Scholar

Copyright information

© Akadémiai Kiadó 1981

Authors and Affiliations

  • E. S. Rudakov
    • 1
  1. 1.Institute of Physical Organic and Coal ChemistryDonetskUSSR

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