Advertisement

Zeitschrift für Physik A Hadrons and nuclei

, Volume 263, Issue 4, pp 315–328 | Cite as

d1 Electrons in amorphous semiconducting V2O5 and MoO3 compounds. (ESR measurements)

  • G. Sperlich
  • P. Urban
  • G. Frank
Article

Abstract

We have performed electron spin resonance experiments on binary amorphous V2 O5- and MoO3 compounds (V2O5-TeO2, V2O5-BaO, V2O5-PbO, V2O5-GeO2, V2O5-As2O3, MoO3-P2O5, MoO3-TeO2) and determined the parameters of the corresponding spin Hamiltonian by 3 cm-, 1.2 cm- and 8 mm band measurements. These measurements yielded values of the contribution to the mean energy difference of thed1 levels between different vanadium- or molybdenum sites caused by fluctuations of the crystal field.

Keywords

Vanadium Molybdenum Electron Spin Resonance Elementary Particle MoO3 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Baynton, P. L., Rawson, H., Stanworth, I. E.: J. Electrochem. Soc.104, 237 (1955)CrossRefGoogle Scholar
  2. 2.
    Lynch, G. F., Sayer, M., Segal, S. L., Rosenblatt, G.: J. Appl. Phys.42, 2587 (1971)ADSCrossRefGoogle Scholar
  3. 3.
    Austin, I. G., Mott, N. F.: Advan. Phys.18, 41 (1969)ADSCrossRefGoogle Scholar
  4. 4.
    Adler, D.: Amorphous semiconductors. London: Butterworths 1972Google Scholar
  5. 5.
    Schmid, A. P.: J. Appl. Phys.39, 3140 (1968)ADSCrossRefGoogle Scholar
  6. 6.
    Sayer, M., Mansingh, A., Reyes, J. M., Rosenblatt, G.: J. Appl. Phys.42, 2857 (1971)ADSCrossRefGoogle Scholar
  7. 7.
    Anderson, P. W.: Phys. Rev.109, 1492 (1958)ADSCrossRefGoogle Scholar
  8. 8.
    Nagiev, V. M.: Soviet Phys. Solid State7, 2204 (1966)Google Scholar
  9. 9.
    Sperlich, G.: Z. Physik250, 335 (1972)CrossRefGoogle Scholar
  10. 10.
    Baberschke, K., Rhein, W.: Theses TH Darmstadt, 1971Google Scholar
  11. 11.
    Zamotrinskaya, E. A., Kulemin, N. P.: Izv. VUZ Fiz USSR7, 143 (1969)Google Scholar
  12. 12.
    Joffe, V. A., Patrina, I. B.: Soviet Phys. Solid State10, 639 (1968)Google Scholar
  13. 13.
    Sperlich, G., Frank, G., Rhein, W.: Phys. Stat. Sol.(b)54, 241 (1972)ADSCrossRefGoogle Scholar
  14. 14.
    Joffe, V. A., Patrina, I. B., Zelenetskaya, E. V., Mikheeva, V. P.: Phys. Stat. Sol.35, 535 (1969)ADSCrossRefGoogle Scholar
  15. 15.
    Ballhausen, C. I., Gray, H. B.: Inorg. Chemistry1, 111 (1962)CrossRefGoogle Scholar
  16. 16.
    Sperlich, G.: Phys. Lett.29A, 191 (1969)Google Scholar

Copyright information

© Springer-Verlag 1973

Authors and Affiliations

  • G. Sperlich
    • 1
  • P. Urban
    • 1
  • G. Frank
    • 1
  1. 1.II. Physikalisches InstitutTechnische Hochschule DarmstadtDarmstadtGermany

Personalised recommendations