Zeitschrift für Physik A Hadrons and nuclei

, Volume 263, Issue 4, pp 315–328 | Cite as

d1 Electrons in amorphous semiconducting V2O5 and MoO3 compounds. (ESR measurements)

  • G. Sperlich
  • P. Urban
  • G. Frank


We have performed electron spin resonance experiments on binary amorphous V2 O5- and MoO3 compounds (V2O5-TeO2, V2O5-BaO, V2O5-PbO, V2O5-GeO2, V2O5-As2O3, MoO3-P2O5, MoO3-TeO2) and determined the parameters of the corresponding spin Hamiltonian by 3 cm-, 1.2 cm- and 8 mm band measurements. These measurements yielded values of the contribution to the mean energy difference of thed1 levels between different vanadium- or molybdenum sites caused by fluctuations of the crystal field.


Vanadium Molybdenum Electron Spin Resonance Elementary Particle MoO3 


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Copyright information

© Springer-Verlag 1973

Authors and Affiliations

  • G. Sperlich
    • 1
  • P. Urban
    • 1
  • G. Frank
    • 1
  1. 1.II. Physikalisches InstitutTechnische Hochschule DarmstadtDarmstadtGermany

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