Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Kinetics and mechanism of the acid catalytic hydrolysis of 1-alkylthio-1-buten-3-ynes

  • 20 Accesses

Conclusions

The kinetics of the acid catalytic hydrolysis of 1-alkylthio-1-buten-3-ynes was studied, and it was shown that the reaction includes a step of protonation of the triple bond and the formation of the H2C=\(\mathop C\limits^ + \)CH =CHSR cation, which is further converted into two directions with the formation of acetoacetaldehyde and alkylthiobutenone.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    A. N. Khudyakova, A. N. Volkov, and B. A. Trofimov, Reakts. Sposobnost' Organ. Soed.,10, 987 (1973).

  2. 2.

    M. F. Shostakovskii, A. V. Bogdanova, and G. I. Plotnikova, Dokl. Akad. Nauk SSSR,120 301 (1958);124 107 (1959).

  3. 3.

    A. N. Dolgikh, A. V. Bogdanova, G. I. Plotaikova, T. M. Ushakova, and M. F. Shostakovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 127 (1964).

  4. 4.

    B. A. Trofimov, N. I. Shergina, É. I. Kositsina, E. P. Vyalykh, S. V. Amosova, N. K. Gusarova, and M. G. Voronkov, Reakts. Sposobnost' Organ. Soed.,10, 757 (1973).

  5. 5.

    B. A. Trofimov, M. F. Shostakovskii, I. S. Emel'yanov, A. S. Atavin, B. V. Prokop'ev, and T. V. Kashik, Reakts. Sposobnost' Organ. Soed.,6, 492 (1969).

Download references

Author information

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1975–1979, September, 1975.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Khudyakova, A.N., Volkov, A.N., Trofimov, B.A. et al. Kinetics and mechanism of the acid catalytic hydrolysis of 1-alkylthio-1-buten-3-ynes. Russ Chem Bull 24, 1856–1860 (1975). https://doi.org/10.1007/BF00930151

Download citation

Keywords

  • Hydrolysis
  • Triple Bond
  • Catalytic Hydrolysis
  • Acid Catalytic Hydrolysis