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Complex formation in the system tin(IV)-molybdenum(VI)

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Conclusions

  1. 1.

    Complex formation was studied spectrophotometrically in the system tin(IV)-molybdenum(VI), and the existence of a molybdenum-tin heteropoly compound in weakly acid aqueous solutions was demonstrated; the optimum conditions of its formation were found.

  2. 2.

    The composition of the complex was determined by the method of isomolar series, by the Bjerrum method, as well as by the method of shift of equilibrium, and the conditional stability constant was calculated.

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Literature cited

  1. 1.

    F. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, Wiley (1962).

  2. 2.

    E. Friedländer, Gmelins Handbuch der anorganischen Chemie, Molibdän, Berlin,53, 376 (1935).

  3. 3.

    O. A. Dragomiretskaya, Yu. F. Shkaravskii, and A. T. Pilipenko, Zh. Neorgan. Khim.,16, 2736 (1971).

  4. 4.

    A. K. Babko and Yu. F. Shkaravskii, Zh. Neorgan. Khim.,6, 2091 (1961).

  5. 5.

    F. P. Sudakov, L. A. Obukhova, and T. I. Tsenskaya, Zh. Analiticheskoi Khim.,25, 765 (1970).

  6. 6.

    A. Rosenheim, M. Pick, and P. Pinsker, Z. Anorgan. und allgem. Chem.,96, 151 (1916).

  7. 7.

    P. Cannon, J. Inorg. and Nucl. Chem.,9, 252 (1959).

  8. 8.

    E. Richardson, J. Inorg. and Nucl. Chem.,9, 267 (1959).

  9. 9.

    Ku Tkhan' Long, Dissertation [in Russian], Moscow (1964).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1919–1922, September, 1975.

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Morosanova, S.A., Muzykantova, V.N., Shkatova, L.A. et al. Complex formation in the system tin(IV)-molybdenum(VI). Russ Chem Bull 24, 1801–1803 (1975). https://doi.org/10.1007/BF00930139

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Keywords

  • Aqueous Solution
  • Optimum Condition
  • Molybdenum
  • Complex Formation
  • Stability Constant