The diesters of mono-α-alkyl- andα,α-dialkyldicarboxylic acids were obtained by the telomerization of ethylene with the dimethyl esters of succinic and adipic acids.
Rearrangement of the radicals, with a 1,5-migration of the hydrogen atoms, occurs during the telomerization of the dimethyl ester of adipic acid.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1527–1530, July, 1973.
The authors are indebted to V. I. Dostovalova for taking and discussing the spectra.
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Terent'ev, A.B., Freidlina, R.K. Telomerization of ethylene with dicarboxylic esters. Russ Chem Bull 22, 1480–1482 (1973). https://doi.org/10.1007/BF00930042
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