Nickel, modified by D(+)-tartaric acid, leads to the asymmetric hydrogenation of O-acetylacetophenone oxime in an optical yield of 0.2%.
The dissymmetric catalyst, obtained by decomposing the complex trans-dichloro-bis-S-α-phenylethylaminepalladium (II), leads to the asymmetric hydrogenation of acetophenone oxime in an optical yield of 3.5%.
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E. I. Klabunovskii and E. S. Levitina, Usp. Khim.,39, 2154 (1970).
S. Akabori, S. Sakurai, Y. Izumi, and Y. Fujii, Nature,178, 323 (1965);22, 154 (1957).
T. Isoda, A. Ishikawa, and T. Shimamoto, Repts. Scient. Res. Inst.,34, 134, 143 (1958); Chem. Abstrs.,54, 287 (1960).
Y. Izumi, M. Imaida, H. Fukawa, and S. Akabori, Bull. Chem. Soc. Japan,36, 21, 155 (1963).
Yu. I. Petrov, E. I. Klabunovskii, and A. A. Balandia, Kinetika i Kataliz,8, 814 (1967).
Y. Izumi, H. Takizawa, K. Nakagawa, R. Imamura, M. Imaida, T. Ninomiga, and I. Yajima, Bull. Chem. Soc. Japan,43, 1792 (1970).
B. Bosnich, J. Chem. Soc., A, 1394 (1966).
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2354–2357, October, 1975.
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Neupokoeva, E.S., Karpeiskaya, E.I., Godunova, L.F. et al. Asymmetric hydrogenation of C = N bond on dissymmetric nickel and palladium catalysts. Russ Chem Bull 24, 2241–2243 (1975). https://doi.org/10.1007/BF00929772
- Tartaric Acid