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Generation and some reactions of bis(trifluoromethyl)aza anion

Conclusions

  1. 1.

    Perfluoro-2-azapropene when passed through a suspension of alkali-metal fluorides in aprotic polar solvents generates the bis(trifluoromethyl)aza anion.

  2. 2.

    Reactions involving (CF3)3N are a convenient way of inserting the bis(trifluoromethyl)amino group into various organic compounds.

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Literature cited

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    R. D. Dresdner, F. N. Tlumac, and J. A. Young, J. Org. Chem.,30, 3524 (1965).

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    R. D. Smith, F. S. Fawcett, and D. D. Coffman, J. Amer. Chem. Soc.,84, 4285 (1962).

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    R. D. Dresdner and J. A. Young, J. Org. Chem.,32, 2004 (1967).

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    A. F. Gontar, É. G. Bykhovskaya, and I. L. Knunyants, Zb. Vses. Khim. Obshchestva im. D. I. Mendeleeva,20, 232 (1970).

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    J. A. Young, R. D. Dresdner, and V. S. Durrell, J. Amer. Chem. Soc.,84, 1547 (1959).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2279–2282, October, 1975.

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Gontar', A.F., Bykhovskaya, É.G. & Knunyants, I.L. Generation and some reactions of bis(trifluoromethyl)aza anion. Russ Chem Bull 24, 2161–2164 (1975). https://doi.org/10.1007/BF00929745

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Keywords

  • Fluoride
  • Organic Compound
  • Polar Solvent
  • Trifluoromethyl
  • Aprotic Polar Solvent