Perfluoro-2-azapropene when passed through a suspension of alkali-metal fluorides in aprotic polar solvents generates the bis(trifluoromethyl)aza anion.
Reactions involving (CF3)3N− are a convenient way of inserting the bis(trifluoromethyl)amino group into various organic compounds.
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Gontar', A.F., Bykhovskaya, É.G. & Knunyants, I.L. Generation and some reactions of bis(trifluoromethyl)aza anion. Russ Chem Bull 24, 2161–2164 (1975). https://doi.org/10.1007/BF00929745
- Organic Compound
- Polar Solvent
- Aprotic Polar Solvent