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Synthesis of bacterial antigenic polysaccharides and their fragments 9. Synthesis of the trisaccharide repeating unit of the O-specific polysaccharide of Salmonella newington with a radioactive label in the mannose residue

Conclusions

The total acetate of β-D-mannopyranosyl-2-3H-(1 → 4)-α-L-rhamnopyranosyl-(1 ρ 3)-D-galactopyranose] has been synthesized by introducing the radioactive label into the mannose residue during NaBH4-3H reduction of 4-0-(3,4,6-tri-O-benzyl-β-D-arabinohexylosopyranosyl)-2,3-O-isopropylidene-α-benzyl-L-rhamnoside.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2124–2128, September, 1978.

The authors wish to thank N. É. Bairamova, M. V. Ovchinnikov, and V. I. Torgov for supplying the starting materials and for valuable consultations.

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Shibaev, V.N., Chekunchikov, V.N. & Kochetkov, N.K. Synthesis of bacterial antigenic polysaccharides and their fragments 9. Synthesis of the trisaccharide repeating unit of the O-specific polysaccharide of Salmonella newington with a radioactive label in the mannose residue. Russ Chem Bull 27, 1876–1879 (1978). https://doi.org/10.1007/BF00929243

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Keywords

  • Acetate
  • Polysaccharide
  • Mannose
  • Radioactive Label
  • Trisaccharide