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The mechanism of benzaldehyde oxidation by ozonated oxygen

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Conclusions

  1. 1.

    A study has been made of the autooxidation of benzaldehyde. The results obtained indicate that chain initiation in this reaction follows a trimolecular mechanism with a rate constant k equal to 5.4·10−5 liter2/mole2·sec (27°C).

  2. 2.

    A study has also been made of the kinetics of the benzaldehyde oxidation by ozonated oxygen, and of the products obtained from this reaction. A mechanism has been proposed for this process, and rate constants and efficiencies of initiation measured.

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Literature cited

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    E. Briner, Adv. Chem. Ser.,21, 184 (1959).

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    N. M. Émanuél', E. T. Denisov, and Z. K. Maizus, Chain Hydrocarbon Oxidation Reactions in the Liquid Phase [in Russian], Nauka (1965), p. 176.

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    E. T. Denisov, N. I. Mitskevich, and V. E. Agabekov, Mechanism of Liquid-Phase Oxidation of Oxygen-Containing Compounds [in Russian], Nauka i Tekhnika, Minsk (1975), p. 103.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1991–1996, September, 1978.

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Komissarova, I.N., Komissarov, V.D. & Denisov, E.T. The mechanism of benzaldehyde oxidation by ozonated oxygen. Russ Chem Bull 27, 1751–1756 (1978). https://doi.org/10.1007/BF00929217

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Keywords

  • Oxidation
  • Oxygen
  • Benzaldehyde
  • Chain Initiation
  • Ozonated Oxygen