A study has been made of the autooxidation of benzaldehyde. The results obtained indicate that chain initiation in this reaction follows a trimolecular mechanism with a rate constant k equal to 5.4·10−5 liter2/mole2·sec (27°C).
A study has also been made of the kinetics of the benzaldehyde oxidation by ozonated oxygen, and of the products obtained from this reaction. A mechanism has been proposed for this process, and rate constants and efficiencies of initiation measured.
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Komissarova, I.N., Komissarov, V.D. & Denisov, E.T. The mechanism of benzaldehyde oxidation by ozonated oxygen. Russ Chem Bull 27, 1751–1756 (1978). https://doi.org/10.1007/BF00929217
- Chain Initiation
- Ozonated Oxygen