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Reaction of carbon dioxide with ditolyltitanocenes under thermal decomposition conditions

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Conclusions

The reaction of CO2 with ditolyltitanocenes under thermolysis conditions proceeds in two directions: insertion of CO2 at the Ti-C6H4CH3 bonds and the reaction of CO2 with the dehydrotoluene complex of the titanocene, which is formed by the decomposition of Cp2Ti(p-CH3C6H4)2 and Cp2Ti(m-CH3C6H4)2.

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1177–1180, May, 1978.

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Grigoryan, M.K., Kolomnikov, I.S., Berkovich, É.G. et al. Reaction of carbon dioxide with ditolyltitanocenes under thermal decomposition conditions. Russ Chem Bull 27, 1024–1026 (1978). https://doi.org/10.1007/BF00929019

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Keywords

  • Dioxide
  • Carbon Dioxide
  • Thermal Decomposition
  • Thermolysis
  • Titanocene