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Reaction of dialkylphosphorous acids with 2,2-dimethyl-1,3-indandione

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  1. 1.

    The reaction of 2,2-dimethyl-1,3-indandione with diethyl- and di-n-butylphosphorous acids in the presence of amines gave 2,2-dimethyl-3-hydroxyindan-1-one-3-diethylphosphonate and 2,2-dimethyl-3-hydroxyindan-1-one-3-di-n-butylphosphonate.

  2. 2.

    The phosphonate-phosphate isomerization of 2,2-dimethyl-3-hydroxyindan-1-one-3-diethylphosphonate to 2,2-dimethylindan-1-one-3-diethylphosphate was detected at room temperature in the presence of amines.

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Literature cited

  1. 1.

    B. A. Arbuzov and N. P. Bogonostseva, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk,1954, 837.

  2. 2.

    A. N. Pudovik, I. V. Gur'yanova, and É. A. Ishmaeva, Study Methods and Reaction of Organic Compounds [in Russian], “Khimiya” (1968), p. 19.

  3. 3.

    B. A. Arbuzov, N. P. Bogonostseva, I. D. Neklesova, N. N. Batyrshin, and V. Yu. Tereshchenko, USSR Patent 436, 574, March21, 1974; Byull. Izobr., No. 11, 195 (1976); USSR Patent 431,172, Feb.14, 1974; Byull, Izobr., No.21, 86 (1974).

  4. 4.

    W. Wislicenus and A. Kötzle, Ann. Chem.,252, 80 (1889).

  5. 5.

    A. Aebi, E. Gyurech-Vago, E. Hofstetter, and P. Waser, Pharm. Acta Helv.,38, 407 (1963).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1416–1418, June, 1976.

The authors thank É. I. Gol'dfarb for taking the31P NMR spectra.

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Arbuzov, B.A., Bogonoseva, N.P. & Vinogradova, V.S. Reaction of dialkylphosphorous acids with 2,2-dimethyl-1,3-indandione. Russ Chem Bull 25, 1358–1360 (1976).

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  • Diethyl
  • Indandione
  • Dialkylphosphorous Acid