Advertisement

Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Reaction of dialkylphosphorous acids with 2,2-dimethyl-1,3-indandione

  • 19 Accesses

  • 2 Citations

Conclusions

  1. 1.

    The reaction of 2,2-dimethyl-1,3-indandione with diethyl- and di-n-butylphosphorous acids in the presence of amines gave 2,2-dimethyl-3-hydroxyindan-1-one-3-diethylphosphonate and 2,2-dimethyl-3-hydroxyindan-1-one-3-di-n-butylphosphonate.

  2. 2.

    The phosphonate-phosphate isomerization of 2,2-dimethyl-3-hydroxyindan-1-one-3-diethylphosphonate to 2,2-dimethylindan-1-one-3-diethylphosphate was detected at room temperature in the presence of amines.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    B. A. Arbuzov and N. P. Bogonostseva, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk,1954, 837.

  2. 2.

    A. N. Pudovik, I. V. Gur'yanova, and É. A. Ishmaeva, Study Methods and Reaction of Organic Compounds [in Russian], “Khimiya” (1968), p. 19.

  3. 3.

    B. A. Arbuzov, N. P. Bogonostseva, I. D. Neklesova, N. N. Batyrshin, and V. Yu. Tereshchenko, USSR Patent 436, 574, March21, 1974; Byull. Izobr., No. 11, 195 (1976); USSR Patent 431,172, Feb.14, 1974; Byull, Izobr., No.21, 86 (1974).

  4. 4.

    W. Wislicenus and A. Kötzle, Ann. Chem.,252, 80 (1889).

  5. 5.

    A. Aebi, E. Gyurech-Vago, E. Hofstetter, and P. Waser, Pharm. Acta Helv.,38, 407 (1963).

Download references

Author information

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1416–1418, June, 1976.

The authors thank É. I. Gol'dfarb for taking the31P NMR spectra.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Arbuzov, B.A., Bogonoseva, N.P. & Vinogradova, V.S. Reaction of dialkylphosphorous acids with 2,2-dimethyl-1,3-indandione. Russ Chem Bull 25, 1358–1360 (1976). https://doi.org/10.1007/BF00928098

Download citation

Keywords

  • Diethyl
  • Indandione
  • Dialkylphosphorous Acid