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Acetoxy derivatives of trans-1,2-disilylethylene and their hydrolysis

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Conclusions

A method was developed for the synthesis of acetoxy-trans-1,2-disilylethylenes of formula (CH3COO)n(CH3)2−nRSiCH=CHSi(CH3)R′(OCOCH3), where R and R′=alkyl, and n=0 or 1. The corresponding silanols were obtained by the hydrolysis of the latter.

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Literature cited

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    M. G. Voronkov, O. G. Yarosh, V. A. Pestunovich, M. V. Sigalov, and L. V. Tsvetaeva, Izv. Akad. Nauk SSSR, Ser. Khim.,1974, 2066.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1395–1397, June, 1976.

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Voronkov, M.G., Yarosh, O.G., Shchukina, L.V. et al. Acetoxy derivatives of trans-1,2-disilylethylene and their hydrolysis. Russ Chem Bull 25, 1338–1340 (1976). https://doi.org/10.1007/BF00928090

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Keywords

  • Hydrolysis
  • Acetoxy
  • Acetoxy Derivative