The hydride addition of hydrosiloxanes to alkyl(aryl)vinylcyclotetrasiloxanes gave a number of organocyclotetrasiloxanes, which have siloxane chainlets with terminal trimethylsilyl groups as the framing radicals.
The polymerization of organocyclotetrasiloxanes, with carbosiloxane groups as the radicals, in the presence of ionic catalysts leads to the formation of polymers with a crosslinked structure.
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V. T. Tsyba and Yu. P. Egorov, in the monograph “Applied Spectroscopy” (Data of Sixteenth Convention, Moscow, 1965) [in Russian], Vol. 2, Nauka (1969), p. 110.
A. A. Zhdanov, K. A. Andrianov, T. V. Astapova, and G. F. Vinogradova, Izv. Akad. Nauk SSSR, Ser. Khim.,1973, 2628.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 129–131, January, 1975.
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Andrianov, K.A., Kotov, V.M. & Pryakhina, T.A. Synthesis of organocyclotetrasiloxanes with carbosiloxane groups. Russ Chem Bull 24, 117–119 (1975). https://doi.org/10.1007/BF00926304
- Trimethylsilyl Group