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The kinetics and mechanism of the reaction of ozone with phenol in aqueous solution

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Conclusions

  1. 1.

    Ozone reacts with phenol in aqueous solution, attacking the phenol group and opening the aromatic ring.

  2. 2.

    The reaction follows a bimolecular rate law over the entire range of ozone and phenol concentrations.

  3. 3.

    The Arrhenius parameters for reaction in water are anomalously high in comparison with the parameters for this same reaction in nonaqueous solution.

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Literature cited

  1. 1.

    L. I. Kashtanov and O. N. Oleshuk, Zh. Obshch. Khim.,7, 1413 (1937).

  2. 2.

    H. R. Eisenhauer, J. Water Pollut. Control Fed.,40, 1884 (1968).

  3. 3.

    E. Bernatek and A. Vinze, Acta Chem. Scand.,15, 471 (1961);19, 2207 (1965).

  4. 4.

    V. T. Kaplin, E. I. Perel'shtein, and N. G. Fesenko, Gidrokhim. Mater.,42, 274 (1966);46, 199 (1968).

  5. 5.

    S. D. Razumovskii, G. A. Nikiforov, G. M. Globenko, A. A. Kefeli, Ya. A. Gurvich, N. A. Karlei, and G. E. Zaikov, Neftekhimiya,12, 376 (1972).

  6. 6.

    S. D. Razumovskii, G. M. Globenko, G. A. Nikiforov, Ya. A. Gurvich, N. A. Kareli, and G. E. Zaikov, Neftekhimiya,12, 65 (1972).

  7. 7.

    S. D. Razumovskii, L. V. Ruban, G. S. Nikiforov, Ya. A. Gurvich, E. I. Shatokhina, and G. E. Zaikov, Neftekhimiya,13, 101 (1973).

  8. 8.

    E. Gilbert, Vom Wasser 1974,Weinfeim 1972,43, 275.

  9. 9.

    S. L. Niegowsky, Ind. Eng. Chem.,45, 632 (1953).

  10. 10.

    I. I. Rozhnyatovskii, D. N. Dubrovskaya, and F. A. Melamed, Koks Khim., No. 7, 63 (1959).

  11. 11.

    P. N. Kandzas and A. A. Mokina, Zh. Vses. Khim. O-va,17, 169 (1972).

  12. 12.

    S. D. Razumovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 335 (1970).

  13. 13.

    V. I. Matrozov, S. A. Kashtanov, A. M. Stepanov, and B. A. Tregubov, Zh. Prikl. Khim.,48, 1838 (1975).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 285–288, February, 1979.

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Razumovskii, S.D., Ovechkin, V.S. & Konstantinova, M.L. The kinetics and mechanism of the reaction of ozone with phenol in aqueous solution. Russ Chem Bull 28, 261–264 (1979). https://doi.org/10.1007/BF00925862

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Keywords

  • Aqueous Solution
  • Phenol
  • Ozone
  • Aromatic Ring
  • Entire Range