Depending on the ratio of the reactants and the reaction temperature, the reaction of benzenesulfonyl chloride with sodium trialkylsilylalkylthiolates R3Si(CH2)nSNa (R=Me, Et; n=1–3) leads either to labile S-phenyl S′-trialkylsilylalkyl thiosulfonates or to their mixture with S,S′-bis(trialkylsilylalkyl) disulfides.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 204–205, January, 1979.
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Vlasova, N.N., Bol'shakova, S.A., Skrypnik, Y.G. et al. Reaction of trialkylsilylalkanethiols with benzenesulfonyl chloride. Russ Chem Bull 28, 190–191 (1979). https://doi.org/10.1007/BF00925422
- Reaction Temperature