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Reaction of trialkylsilylalkanethiols with benzenesulfonyl chloride

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Conclusions

Depending on the ratio of the reactants and the reaction temperature, the reaction of benzenesulfonyl chloride with sodium trialkylsilylalkylthiolates R3Si(CH2)nSNa (R=Me, Et; n=1–3) leads either to labile S-phenyl S′-trialkylsilylalkyl thiosulfonates or to their mixture with S,S′-bis(trialkylsilylalkyl) disulfides.

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Literature cited

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    N. N. Vlasova, L. N. Kulikova, E. O. Tsetlina, and M. G. Voronkov, Zh. Obshch. Khim.,44, 2159 (1974).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 204–205, January, 1979.

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Vlasova, N.N., Bol'shakova, S.A., Skrypnik, Y.G. et al. Reaction of trialkylsilylalkanethiols with benzenesulfonyl chloride. Russ Chem Bull 28, 190–191 (1979). https://doi.org/10.1007/BF00925422

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Keywords

  • Sodium
  • Chloride
  • Disulfide
  • Reaction Temperature
  • Benzenesulfonyl