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Nucleophilic addition of sulfenyl chlorides to highly electrophilic fluoroolefins

Conclusions

  1. 1.

    When catalyzed by chlorine anion or pyridine, alkyl- or arylsulfenyl chlorides add to perfluoroisobutylene or to methyl perfluoromethacrylate by the nucleophilic mechanism.

  2. 2.

    Perfluoroisobutylene when reacted with either trichloromethyl- or chlorocarbonylsulfenyl chloride in the presence of chlorine anion adds chlorine at the multiple bond.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 946–948, April, 1978.

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Zeifman, Y.V., Lantseva, L.T. & Knunyants, I.L. Nucleophilic addition of sulfenyl chlorides to highly electrophilic fluoroolefins. Russ Chem Bull 27, 820–822 (1978). https://doi.org/10.1007/BF00925319

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Keywords

  • Methyl
  • Chloride
  • Chlorine
  • Pyridine
  • Multiple Bond