Trichloroacetyl isocyanate reacts with cyclopentanone and cyclohexanone to give N-trichloroacetyl-2-carbamidocycloalken-1-y1-1-N′-trichloroacetylurethans.
Acetylacetone, dibenzoylmethane, and ethyl β-cyclopentanonecarboxylate react with trichloroacetyl isocyanate in a 1∶1 ratio to give O,N-substituted derivatives of carbamic acid.
This is a preview of subscription content, log in to check access.
Buy single article
Instant access to the full article PDF.
Price includes VAT for USA
Subscribe to journal
Immediate online access to all issues from 2019. Subscription will auto renew annually.
This is the net price. Taxes to be calculated in checkout.
H. Claus, H. J. Fridrich, and H. Jensen, Ann. Chem.,1974, 561.
A. Hassner and J. K. Rasmussen, J. Am. Chem. Soc.,97, 1451 (1975).
A. N. Kost (editor), General Laboratory Manual on Organic Chemistry [in Russian], Mir (1965), p. 456.
R. Abell, J. Chem. Soc.,101, 998 (1912).
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1910–1912, August, 1977.
About this article
Cite this article
Arbuzov, B.A., Zobova, N.N. & Sofronova, O.V. Reaction of trichloroacetyl isocyanate with some ketones and β-diketones. Russ Chem Bull 26, 1773–1775 (1977). https://doi.org/10.1007/BF00925203