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Photochemical transformations of mercury trifluoroacetates in the solid phase

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Summary

The main primary process of photochemical decompositions of Hg(OCOCF3)2 and CF3HgOCOCF3 in the solid phase between −196 and +20°C is decarboxylation, accompanied by the formation of CF3 radicals, which near the temperature of liquid nitrogen react in the lattice to form trifluoromethyl derivatives of mercury, and at higher temperatures diffuse and dimerize to C2F6.

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Literature cited

  1. 1.

    D. Seyferth, Accounts Chem. Res.,5, 65 (1972); A. K. Mal'tsev, R. G. Mikaélyan, and O. M. Nefedov, Dokl. Akad. Nauk SSSR,201, 901 (1971).

  2. 2.

    I. L. Knunyants, Ya. F. Komissarov, B. L. Dyatkin, and L. T. Lantseva, Izv. Akad. Nauk SSSR, Ser. Khim., 943 (1973).

  3. 3.

    A. K. Mal'tsev, N. D. Kagramanov, and O. M. Nefedov, Izv. Akad. Nauk SSSR, Ser. Khim 1993 (1974).

  4. 4.

    A. K. Mal'tsev, N. D. Kagramanov, and O. M. Nefedov, Dokl. Akad. Nauk SSSR, 224, 630 (1975).

  5. 5.

    W. Kirmse, Chemistry of Carbenes [Russian translation], Mir (1966).

  6. 6.

    G. A. Razuvaev and Yu. A. Ol'dekop, Dokl. Akad. Nauk SSSR,105, 738 (1955).

  7. 7.

    N. A. Maier, Dissertation, Minsk, 1974.

  8. 8.

    A. K. Mal'tsev, R. G. Mikaélyan, and O. M. Nefedov, Prib. Tekh. Éksp., No. 1, 249 (1971).

  9. 9.

    A. J. Downs, E. A. V. Ebsworth, and H. J. Emeléus, J. Chem. Soc., 1254 (1962).

  10. 10.

    L. M. Sverdlov, M. A. Kovner, and E. P. Krainov, Vibration and Rotation Spectra of Polyatomic Molecules [in Russian], Nauka (1970).

  11. 11.

    M. B. Fagarash and F. B. Moin, Kinet. Katal.,13, 274 (1972).

  12. 12.

    L. M. Quick and E. Whittle, Trans. Faraday Soc. 1, 878 (1972).

  13. 13.

    A. Snelson, High Temp. Sci.,2, 70 (1970).

  14. 14.

    V. G. Seleznev, G. A. Skorobogatov, and V. S. Komarov, Zh. Obshch. Khim.,44, 1293 (1974).

  15. 15.

    P. E. Aldrich, U. S. Pat. 3043859; Chem. Abstr.,57, 14944 (1962).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1835–1839, August, 1977.

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Kagramanov, N.D., Mal'tsev, A.K. & Nefedov, O.M. Photochemical transformations of mercury trifluoroacetates in the solid phase. Russ Chem Bull 26, 1697–1700 (1977). https://doi.org/10.1007/BF00925179

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Keywords

  • Nitrogen
  • Mercury
  • Liquid Nitrogen
  • Trifluoromethyl
  • Primary Process