During the reaction of 1-methoxy-3-iminoisoindole and phthalodinitrile with m- and p-phenylenediamine in PPhA, no macroheterocycle is formed.
During the reaction of 1-methoxy-3-iminoisoindole and phthalodinitrile with anthranilic acid in PPhA, compounds are formed which contain isoindole and quinazoline rings.
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S. V. Vinogradova, V. V. Korshak, B. V. Rozynov, and S. A. Siling, Zh. Org. Khim.,8, 1305 (1972).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1871–1877, August, 1978.
The authors with to express their gratitude to S. V. Vinogradova for her constant interest in their work and for discussion of the results, and also to the mass spectrometry group for running the spectra.
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Siling, S.A., Ponomarev, I.I. Reactions of phthalodinitrile with aromatic diamines in polyphosphoric acid. Russ Chem Bull 27, 1643–1649 (1978). https://doi.org/10.1007/BF00925057
- Anthranilic Acid
- Polyphosphoric Acid
- Aromatic Diamine