Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Reaction of carbene of cyclohexadienone type with multiple bonds of conjugated dienes

  • 34 Accesses

  • 2 Citations

Conclusions

  1. 1.

    The 1,2-addition products are formed initially when the cyclohexadienone carbene is reacted with the multiple bonds of conjugated dienes, which are isomerized under the conditions for the thermolysis of the quinone diazide, but are stable under photolysis conditions at 5–7°.

  2. 2.

    The rate of the thermal isomerization of the 1,2-addition products was studied.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    G. A. Nikiforov, B. D. Sviridov, and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 558 (1968).

  2. 2.

    B. D. Sviridov, G. A. Nikiforov, and V. V. Ershov, ibid., 1862 (1969).

  3. 3.

    B. D. Sviridov, G. A. Nikiforov, and V. V. Ershov, ibid., 2388 (1970).

  4. 4.

    V. S. Aksenov, in: Contemporary Problems in Organic Chemistry [in Russian], K. A. Ogloblina (editor), LGU (1971), p. 16.

  5. 5.

    I. S. Belostotskaya, Dissertation [in Russian], Moscow (1968).

  6. 6.

    H. Frey, Trans. Faraday Soc.,58, 516 (1962).

  7. 7.

    M. Flawers and H. Frey, J. Chem. Soc., 3547 (1961).

Download references

Author information

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 373–377, February, 1974.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Nikiforov, G.A., Sviridov, B.D. & Ershov, V.V. Reaction of carbene of cyclohexadienone type with multiple bonds of conjugated dienes. Russ Chem Bull 23, 339–342 (1974). https://doi.org/10.1007/BF00924683

Download citation

Keywords

  • Quinone
  • Diene
  • Photolysis
  • Carbene
  • Thermolysis