The 1,2-addition products are formed initially when the cyclohexadienone carbene is reacted with the multiple bonds of conjugated dienes, which are isomerized under the conditions for the thermolysis of the quinone diazide, but are stable under photolysis conditions at 5–7°.
The rate of the thermal isomerization of the 1,2-addition products was studied.
This is a preview of subscription content, log in to check access.
Buy single article
Instant access to the full article PDF.
Price includes VAT for USA
Subscribe to journal
Immediate online access to all issues from 2019. Subscription will auto renew annually.
This is the net price. Taxes to be calculated in checkout.
G. A. Nikiforov, B. D. Sviridov, and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 558 (1968).
B. D. Sviridov, G. A. Nikiforov, and V. V. Ershov, ibid., 1862 (1969).
B. D. Sviridov, G. A. Nikiforov, and V. V. Ershov, ibid., 2388 (1970).
V. S. Aksenov, in: Contemporary Problems in Organic Chemistry [in Russian], K. A. Ogloblina (editor), LGU (1971), p. 16.
I. S. Belostotskaya, Dissertation [in Russian], Moscow (1968).
H. Frey, Trans. Faraday Soc.,58, 516 (1962).
M. Flawers and H. Frey, J. Chem. Soc., 3547 (1961).
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 373–377, February, 1974.
About this article
Cite this article
Nikiforov, G.A., Sviridov, B.D. & Ershov, V.V. Reaction of carbene of cyclohexadienone type with multiple bonds of conjugated dienes. Russ Chem Bull 23, 339–342 (1974). https://doi.org/10.1007/BF00924683