Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Vibrational spectra and force fields of (CH3)3six-type molecules 2. Spectroscopic study and vibration calculations on trimethylsilane, trimethylfluorosilane, and trimethylbromosilane

  • 24 Accesses

  • 2 Citations

Conclusions

  1. 1.

    It has been shown that the Si-F bond vibration interacts with the (CH3)3Si group vibrations in trimethylfluorosilane and its deuterated analog. It has also been shown that there is Fermi resonance between the Si-Br bond vibration overtone and the (CD3)3Si-group vibrations in deuterated trimethylbromosilane.

  2. 2.

    The results of vibration calculations on trimethylsilane, trimethylfluorosilane, and trimethylbromosilane show that the (CH3)3Si-group force-field model can be applied to the analysis of the spectra of these compounds.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    A. N. Lazarev and T. F. Tenisheva, Izv. Akad. Nauk SSSR, Ser. Khim., 338 (1978).

  2. 2.

    H. Kriegsmann, Z. Anorg. Allg. Chem.,294, 113 (1958).

  3. 3.

    H. Bürger, Spectrochim. Acta,24A, 2015 (1968).

  4. 4.

    D. F. Ball, P. L. Goggin, D. C. McKean, and L. A. Woodward, Spectrochim. Acta,16, 1358 (1960).

  5. 5.

    H. Bürger, Organometall. Chem. Rev.,A3, 425 (1968).

  6. 6.

    T. F. Tenisheva, A. N. Lazarev, and R. I. Uspenskaya, J. Mol. Struct.,37, 173 (1977).

Download references

Author information

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 344–350, February, 1978.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Tenisheva, T.F., Lazarev, A.N. & Uspenskaya, R.I. Vibrational spectra and force fields of (CH3)3six-type molecules 2. Spectroscopic study and vibration calculations on trimethylsilane, trimethylfluorosilane, and trimethylbromosilane. Russ Chem Bull 27, 296–301 (1978). https://doi.org/10.1007/BF00923863

Download citation

Keywords

  • Force Field
  • Spectroscopic Study
  • Vibrational Spectrum
  • Bond Vibration
  • Fermi Resonance