IR spectra for decaborane(12) diammoniate, and the products obtained at various stages in its decomposition, have been analyzed and interpreted.
The decomposition of decaborane(12) diammoniate probably proceeds through formation of a covalent B-N bond from a donor-acceptor B ← N bond.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 334–338, February, 1978.
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Rozenberg, A.S. Decomposition of nitrogen-hydrogen complexes of decaborane(12). 2. An IR study of the mechanism of decomposition of decaborane(12) diammoniate. Russ Chem Bull 27, 287–290 (1978). https://doi.org/10.1007/BF00923861