When the Meerwein ester and the dimethyl ester of bicyclo[3.3.1]nonane-2,6-dione-3,7-dicar-boxylic acid are brominated in bromine medium the ester groups are replaced by halogen atoms.
Together with the mono- and dibromo derivatives of the bicyclo[3.3.1]nonane, a compound with the noradamantane structure is formed when the Meerwein ester is brominated in a solvent in the light.
This is a preview of subscription content, log in to check access.
Buy single article
Instant access to the full article PDF.
Price includes VAT for USA
Subscribe to journal
Immediate online access to all issues from 2019. Subscription will auto renew annually.
This is the net price. Taxes to be calculated in checkout.
V. D. Sukhoverkhov, Dissertation [in Russian], Kiev (1969).
S. V. Rogozina, Dissertation [in Russian], Moscow (1972).
A. Gagneux and R. Meier, Tetrahedron Lett.,1969, 1365.
H. Stetter, Angew. Chem.,66, 217 (1954).
H. Meerwein, F. Kiel, and C. Klösgen, J. Prakt. Chem.,104, 161 (1922).
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2765–2767, December, 1974.
About this article
Cite this article
Zavarzin, I.V., Klimova, T.A., Krayushkin, M.M. et al. α-Bromo ketones of bicyclo [3.3.1]nonane series communication 1. Russ Chem Bull 23, 2668–2670 (1974). https://doi.org/10.1007/BF00923702