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Mixed chloro-bromo complexes of ruthenium(IV)


Using spectrophotometry the authors have investigated complexing in the system Ru(IV)-Cl-Br. They have identified the formation of mixed-ligand chloro-bromo complexes of Ru(IV) and determined the equilibrium constants of reactions of formation of the complexes [Ru2OCl7Br-(H2O)2]2− and [Ru2OBr7Cl(H2O)2]2−.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2186–2190, October, 1977.

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Pichugina, G.V., Khvostova, V.P. & Alimarin, I.P. Mixed chloro-bromo complexes of ruthenium(IV). Russ Chem Bull 26, 2024–2027 (1977).

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  • Ruthenium
  • Equilibrium Constant
  • Spectrophotometry