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Synthesis of six-membered cyclic compounds, containing the carbon atoms of the o-carborane nucleus and one heteroatom in the ring

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Conclusions

Bis-(o-carboranyl)methoxymethane was synthesized from monolithium-o-carborane and 1,1-dichloro-methyl methyl ether, from which were obtained six-membered carborane heterocycles that contain an aliphatic carbon atom, the four carbon atoms of two o-carborane nuclei, and one heteratom (Si, Sn, Ge, P, and As) in the ring.

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Literature cited

  1. 1.

    Russel N. Grimes, Carboranes, Academic Press, New York-London (1970).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 940–942, April, 1974.

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Zakharkin, L.I., Shemyakin, N.F. Synthesis of six-membered cyclic compounds, containing the carbon atoms of the o-carborane nucleus and one heteroatom in the ring. Russ Chem Bull 23, 910–912 (1974). https://doi.org/10.1007/BF00923540

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Keywords

  • Methyl
  • Ether
  • Carbon Atom
  • Methyl Ether
  • Cyclic Compound