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Thermal decomposition of α-nitroolefins and α-halonitroalkanes in the gas phase

Conclusions

  1. 1.

    The decomposition ofα-nitroolefins andα-halonitroalkanes proceeds by a molecular mechanism.

  2. 2.

    The kinetic characteristics of the homogeneous decomposition of these compounds were determined.

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Literature cited

  1. 1.

    G. M. Nazin, G. B. Manelis, and F. I. Dubovitskii, Usp. Khim.,37, 1443 (1968).

  2. 2.

    V. V. Dubikhin, G. M. Nazin, and G B. Manelis, Izv. Akad. Nauk SSSR, Ser. Khim., 1554 (1971).

  3. 3.

    G. D. Buckley and C. W. Scaife, J. Chem. Soc., 1472 (1947).

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    E. M. Cherkasova and N. N. Mel'nikov, Zh. Obshch. Khim.,19, 322 (1949).

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    P. T. Good and A. Maccoll, J. Chem. Soc., B 268 (1971).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 923–925, April, 1974.

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Dubikhin, V.V., Nazin, G.M. Thermal decomposition of α-nitroolefins and α-halonitroalkanes in the gas phase. Russ Chem Bull 23, 889–891 (1974). https://doi.org/10.1007/BF00923532

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Keywords

  • Molecular Mechanism
  • Thermal Decomposition
  • Kinetic Characteristic
  • Homogeneous Decomposition