Using an equimolar ratio of the reactants, the reaction of bis(cyclopentadienyl)vanadium dichloride with bis(triethylgermyl)cadmium gave a complex of composition [Cp2VCl2·Cd(GeEt3)2].
The complex when heated or reacted with HCl decomposes with the liberation of cadmium (orcadmium chloride) and cleavage of the V-Ge bond.
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G. A. Razuvaev, V. N. Latyaeva, L. I. Vyshinskaya (L. J. Vishinskaya), V. T. Bychkov (Bytchkov), and G. A. Vasilyeva, J. Organomet. Chem.,87, 93 (1975).
V. T. Bychkov, I. V. Lomakova, and G. A. Domrachev, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 2115.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1405–1406, June, 1978.
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Vyshinskaya, L.I., Korneva, S.P. & Cherkasov, V.K. Reaction of bis(cyclopentadienyl)vanadium dichloride with bis(triethylgermy l)cadmium. Russ Chem Bull 27, 1224–1225 (1978). https://doi.org/10.1007/BF00923383
- Equimolar Ratio