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Reaction of 2,6-di-tert-butyl-1,4-benzoquinone diazide with diazoalkanes

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Conclusions

  1. 1.

    The reaction of 2,6-di-tert-butyl-1,4-benzoquinonediazide with diazoalkanes leads to the corresponding azines or N-aminoaziridine hydrazones, the reaction products of azines with dialkanes.

  2. 2.

    The route described for forming the N-aminoaziridine derivatives can serve as a preparative method for their synthesis.

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Literature cited

  1. 1.

    O. P. Studzinskii and I. K. Korobitsina, Usp. Khim.,39, 1754 (1970).

  2. 2.

    P. Schuster and O. Palansky, Monatsh. Chem.,96, 396 (1965).

  3. 3.

    R. Huisgen and R. Fleischmann, Liebigs Ann. Chem.,623, 47 (1959).

  4. 4.

    S. A. Giller, A. V. Eremeev, M. Yu. Lidak, É. É. Liepin'sh, and I. Ya. Kalviln'sh, Khim. Geterotsikl. Soedin.,1971, 2144.

  5. 5.

    V. V. Ershov, G. N. Bogdanov, and A. A. Volod'kin, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk,1963, 157.

  6. 6.

    G. M. Coppinger, Tetrahedron,18, 61 (1962).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1355–1359, June, 1978.

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Bannikov, G.F., Luchinskaya, M.G., Nikiforov, G.A. et al. Reaction of 2,6-di-tert-butyl-1,4-benzoquinone diazide with diazoalkanes. Russ Chem Bull 27, 1179–1182 (1978). https://doi.org/10.1007/BF00923371

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Keywords

  • Benzoquinone
  • Hydrazones
  • Azine
  • Preparative Method
  • Diazide