Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Reaction of 2,6-di-tert-butyl-1,4-benzoquinone diazide with diazoalkanes

  • 29 Accesses


  1. 1.

    The reaction of 2,6-di-tert-butyl-1,4-benzoquinonediazide with diazoalkanes leads to the corresponding azines or N-aminoaziridine hydrazones, the reaction products of azines with dialkanes.

  2. 2.

    The route described for forming the N-aminoaziridine derivatives can serve as a preparative method for their synthesis.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    O. P. Studzinskii and I. K. Korobitsina, Usp. Khim.,39, 1754 (1970).

  2. 2.

    P. Schuster and O. Palansky, Monatsh. Chem.,96, 396 (1965).

  3. 3.

    R. Huisgen and R. Fleischmann, Liebigs Ann. Chem.,623, 47 (1959).

  4. 4.

    S. A. Giller, A. V. Eremeev, M. Yu. Lidak, É. É. Liepin'sh, and I. Ya. Kalviln'sh, Khim. Geterotsikl. Soedin.,1971, 2144.

  5. 5.

    V. V. Ershov, G. N. Bogdanov, and A. A. Volod'kin, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk,1963, 157.

  6. 6.

    G. M. Coppinger, Tetrahedron,18, 61 (1962).

Download references

Author information

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1355–1359, June, 1978.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Bannikov, G.F., Luchinskaya, M.G., Nikiforov, G.A. et al. Reaction of 2,6-di-tert-butyl-1,4-benzoquinone diazide with diazoalkanes. Russ Chem Bull 27, 1179–1182 (1978). https://doi.org/10.1007/BF00923371

Download citation


  • Benzoquinone
  • Hydrazones
  • Azine
  • Preparative Method
  • Diazide