α-Chlorothienyldichlorophosphine was obtained by the reaction ofα-chlorothiophene was phosphorus trichloride in the presence of SnCl4.
α-Chlorothienyldichlorophosphine is alkylated by tetraethyllead at the phosphorus atom to give ethyl-α-chlorothienylchlorophosphine.
A study was made of the reaction of ethyl-α-chlorothienylehlorophosphine with alcohol, diethylamine, acrylic acid, acrylamide, and methacrylamide.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1846–1849, August, 1974.
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Khairullin, V.K., Nesterenko, L.I., Savushkina, V.I. et al. Organophosphorus derivatives of α-chlorothiophene. Russ Chem Bull 23, 1765–1768 (1974). https://doi.org/10.1007/BF00923207
- Acrylic Acid