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Dipole moments of adducts of pyridine and γ-picoline with derivatives of π-allylpalladium chloride

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Conclusions

  1. 1.

    The dipole moment ofπ-allyl complexes of palladium with the composition (RC3H4PdCl)2 and RC3H4PdCl (amine) were measured.

  2. 2.

    The moment of theπ-allyl-palladium bond is 2–2.5 D and is directed from the allyl to the Pd, i. e., the allyl group carries a positive charge in comparison with the metal atom.

  3. 3.

    The observed dipole moments of binuclear complexes agree with the assumption of a disruption of the planar character of the bridge Pd2Cl2 group in solution.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1077–1081, May, 1975.

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Levanda, O.G., Kartsev, G.N., Ignat'eva, S.I. et al. Dipole moments of adducts of pyridine and γ-picoline with derivatives of π-allylpalladium chloride. Russ Chem Bull 24, 986–989 (1975). https://doi.org/10.1007/BF00922948

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Keywords

  • Chloride
  • Pyridine
  • Adduct
  • Palladium
  • Dipole Moment