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Chlorine fluorosulfate

Communication 3. Interaction with hydrogen chloride, nitrogen tetraoxide, sulfur dioxide, carbon monoxide, and tetrachloroethylene

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Conclusions

  1. 1.

    As a result of simple conversion, fluorosulfonic acid, nitronium fluorosulfate, pyrosulfuryl chloride-fluoride, pyrosulfuryl fluoride, and chlorocarbonylfluorosulfate can be obtained from chloride fluorosulfate.

  2. 2.

    Chlorocarbonyl fluorosulfate is capable of interacting smoothly with chlorine fluorosulfate, as well as acylating benzene.

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Literature cited

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    A. V. Fokin, Yu. N. Studnev, L. D. Kuznetsova, and V. L. Rud', Izv. Akad. Nauk SSSR, Ser. Khim., 471 (1974).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1000–1002, May, 1975.

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Fokin, A.V., Nikolaeva, A.D., Studnev, Y.N. et al. Chlorine fluorosulfate. Russ Chem Bull 24, 915–917 (1975). https://doi.org/10.1007/BF00922932

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Keywords

  • Chloride
  • Benzene
  • Fluoride
  • Chlorine
  • Nitronium