The catalyst NiO-SiO2 acquires activity in the reaction of dimerization of C2H4 when Al2O3 is introduced into it.
With increasing Al2O3 content in the catalyst, the conversion of C2H4 and i-C4H8 and the number of electron acceptor centers, recordable by ESR, pass through a maximum (1–3% Al), while the total acidity of the catalyst increases.
This is a preview of subscription content, log in to check access.
Buy single article
Instant access to the full article PDF.
Price includes VAT for USA
Subscribe to journal
Immediate online access to all issues from 2019. Subscription will auto renew annually.
This is the net price. Taxes to be calculated in checkout.
Ya. T. Éidus, K. V. Puzitskii, and B. A. Kazanskii, Izv. Akad. Nauk SSSR, Otd. Khim., 115 (1960).
Ya. T. Éidus, A. L. Lapidus, and R. V. Avetisyan, Izv. Akad. Nauk SSSR, Ser. Khim., 336 (1968).
British Patent 1197878 (1970); Chem. Abstr.,73, 120034 (1970).
German Federal Republic Patent 2051402 (1971); Chem. Abstr.,75, 49489 (1971).
A. V. Frost, Selected Scientific Works [in Russian], Izd-vo Mosk. Un-ta (1960), p. 237.
A. L. Lapidus, R. V. Avetisayn, Ya. I. Isakov, Kh. M. Minachev, and Ya. T. Éidus, Neftekhimiya,10, 648 (1970).
A. Odzaki, H. Ai, and K. Kimura, Fundamentals of the Prediction of Catalytic Action [Russian translation], Vol. 1, Nauka (1970), p. 409.
A. A. Slinkin, M. I. Loktev, and A. M. Rubinshtein, Dokl. Akad. Nauk SSSR,191, 625 (1970).
A. A. Slinkin and M. I. Loktev, Izv. Akad. Nauk SSSR, Ser. Khim., 959 (1970).
M. Goldstein, Experimental Methods of Investigation of Catalysis [Russian translation], Mir (1972), p. 362.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1956–1961, September, 1974.
About this article
Cite this article
Lapidus, A.L., Slinkin, A.A., Rudakova, L.N. et al. Influence of the composition of the catalytic system NiO-SiO2-Al2O3 on its catalytic properties in reactions of oligomerization of ethylene and isobutylene. Russ Chem Bull 23, 1880–1884 (1974). https://doi.org/10.1007/BF00922780