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Unsaturated amines

Communication 15. Mass spectra of aliphatic-aromatic imines


  1. 1.

    The pathways of the decomposition of aliphatic-aromatic imines under the action of electron impact were determined.

  2. 2.

    An influence of substituents in the benzene ring (o-CH3O, p-CH3O, m,p-(CH3O)2, m-CH3O, p-HO, o-HO, o-Cl, p-NO2) and the position of multiple bonds in the aliphatic chain (-CH=NCHh2CH=CH2 or -CH=NCH=CHCH3) on the direction of the fragmentation of imines was established.

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Literature cited

  1. 1.

    Yu. S. Dol'skaya, O. S. Chizhov, and N. I. Golovina, Izv. Akad. Nauk SSSR, Ser. Khim., 2038 (1975).

  2. 2.

    Q. N. Porter and J. Baldas, Mass Spectrometry of Heterocyclic Com., Wiley Interscience, New York (1971), p. 296.

  3. 3.

    D. Goldsmith, D. Becher, S. D. Sample, and C. Djerassi, Tetrahedron,7, 145 (1969).

  4. 4.

    F. Wess, A. Isard, and G. Bonnard, Bull. Soc. Chim. France, 2332 (1965).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2465–2471, November, 1975.

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Chizhov, O.S., Kadentsev, V.I., Dol'skaya, Y.S. et al. Unsaturated amines. Russ Chem Bull 24, 2351–2356 (1975).

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  • Benzene
  • Benzene Ring
  • Electron Impact
  • Aliphatic Chain
  • Multiple Bond