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Kinetic principles of the initiated oxidation of olefins of the bicyclo [2.2.1]heptene series

Conclusions

  1. 1.

    The kinetic principles of the oxidation of the nitrile of bicyclo[2.2.1]hepten5-oic endo(exo) acid and data on the measurement of the chemiluminescence in this process indicate that in the case of initiated oxidation of the nitrile of bicyclo[2.2.1]-hepten-5-oic endo(exo) acid, there is an exchange of inhibitor radicals for olefin radicals, analogously to that observed for other hydrocarbons.

  2. 2.

    A scheme of oxidation of the nitrile of bicyclo[2.2.1]hepten-5-oic endo(exo) acid was proposed, which is in good agreement with the kinetic principles obtained experimentally.

  3. 3.

    The theoretical possibility of epoxidation of the nitrile of bicyclo[2,2,1]hepten5-oic endo(exo) acid by peroxide radicals of isopropylbenzene and ethylbenzene in the joint oxidation of these compounds was demonstrated.

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Literature cited

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2421–2426, November, 1975.

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Filippova, T.B., Belyakov, V.A. & Blyumberg, É.A. Kinetic principles of the initiated oxidation of olefins of the bicyclo [2.2.1]heptene series. Russ Chem Bull 24, 2309–2313 (1975). https://doi.org/10.1007/BF00921638

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Keywords

  • Oxidation
  • Peroxide
  • Hydrocarbon
  • Nitrile
  • Epoxidation