The dependence of the stereochemistry of the cyanohydrin synthesis on the reaction medium was investigated.
The stereospecificity of the reaction is somewhat lowered in a nonionic medium.
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I. N. Nazarov, A. A. Akhrem and A. V. Kamernitskii, Bull. Acad. Sci. USSR, Div. Chem. Sci. 1958, 631.
I. N. Nazarov, A. V. Kamernitskii and A. A. Akhrem, J. Gen. Chem. 28, 1458 (1958).
I. N. Nazarov, A. A. Akhrem and A. V. Kamernitskii, J. Gen. Chem. 25, 1345 (1955).
J. D. Billimoria, J. Chem. Soc. 1953, 2626.
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Kamernitskii, A.V., Akhrem, A.A. Effect of the medium on the stereochemistry of nucleophilic additions at the carbonyl group. Russ Chem Bull 8, 712–714 (1959). https://doi.org/10.1007/BF00915872
- Carbonyl Group
- Reaction Medium
- Nucleophilic Addition
- Nonionic Medium