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Effect of the medium on the stereochemistry of nucleophilic additions at the carbonyl group

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Summary

  1. 1.

    The dependence of the stereochemistry of the cyanohydrin synthesis on the reaction medium was investigated.

  2. 2.

    The stereospecificity of the reaction is somewhat lowered in a nonionic medium.

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Literature cited

  1. [1]

    I. N. Nazarov, A. A. Akhrem and A. V. Kamernitskii, Bull. Acad. Sci. USSR, Div. Chem. Sci. 1958, 631.

  2. [2]

    I. N. Nazarov, A. V. Kamernitskii and A. A. Akhrem, J. Gen. Chem. 28, 1458 (1958).

  3. [3]

    I. N. Nazarov, A. A. Akhrem and A. V. Kamernitskii, J. Gen. Chem. 25, 1345 (1955).

  4. [4]

    J. D. Billimoria, J. Chem. Soc. 1953, 2626.

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Kamernitskii, A.V., Akhrem, A.A. Effect of the medium on the stereochemistry of nucleophilic additions at the carbonyl group. Russ Chem Bull 8, 712–714 (1959). https://doi.org/10.1007/BF00915872

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Keywords

  • Carbonyl
  • Carbonyl Group
  • Reaction Medium
  • Nucleophilic Addition
  • Nonionic Medium