A study was made of the effect of pressure, temperature, and component ratio in the starting mixture on the kinetics of the macroscopic stages of the oxidation of isobutane by oxygen in the presence of HBr.
A chemical mechanism is proposed, which agrees with the kinetic laws of the process.
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A. A. Babaeva, Z. K. Maizus, and N. M. Emanuel, Izvest. Akad. Nauk SSSR, Otdel. Nauk 1378, (1959).
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Z. K. Maizus and N. M. Emanuel', Izvest. Akad. Nauk SSSR, Otdel. Khim. Nauk 2, 182 (1948).
N. M. Emanuel', Problems of Chemical Kinetics, Catalysis, and Reactivity [in Russian] (Moscow, 1955), p. 121.
E. R. Bell, F. H. Dickey, F. F. Rust and W. E. Vaughan. Ind. Eng. Chem. 41, 2597 (1949).
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Babaeva, A.A., Maizus, Z.K. & Émanuél', N.M. Macroscopic stages in the oxidation of isobutane in the presence of hydrogen bromide. Russ Chem Bull 8, 1825–1831 (1959). https://doi.org/10.1007/BF00914752
- Chemical Mechanism