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Monatshefte für Chemie - Chemical Monthly

, Volume 105, Issue 4, pp 787–795 | Cite as

Massenspektrometrische Untersuchung des Substituenteneffektes bei einfach substituierten Benzophenonen

  • R. Heller
  • K. Varmuza
  • P. Krenmayr
Organische Chemie und Biochemie

Mass spectrometric studies of the substituent effect on monosubstituted benzophenones

Abstract

Ionization potentials of benzophenone and six meta- and parasubstituted benzophenones have been measured and correlated withBrownσ+-constants. The ρ-value of this correlation gives evidence that the ionization process of benzophenones is similar to the ionization process of compounds with one benzene ring: removal of an electron from the π-electron system.

Appearance potentials of the benzoyl ions and the corresponding six substituted benzoyl ions have been determined and correlated withHammett σ-constants. The deviations of ions with the substituents m-NH2 and p-NH2 from the correlation line are mainly due to the kinetic shift of these ions.

For the decomposition of benzophenone ions to benzoyl ions the correlation of metastable-ion intensities withHammett σ-constants shows a similar ρ-value as the correlation of the intensities of the decomposition in the ion source.

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Copyright information

© Springer-Verlag 1974

Authors and Affiliations

  • R. Heller
    • 1
  • K. Varmuza
    • 1
  • P. Krenmayr
    • 1
  1. 1.Institut für Allgemeine Chemie der Technischen Hochschule WienWienÖsterreich

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