Advertisement

Monatshefte für Chemie - Chemical Monthly

, Volume 105, Issue 4, pp 735–741 | Cite as

Die Kristallstruktur des Hydrazinium-monofluorids

  • L. Golič
  • F. Lazarini
Anorganische, Struktur- und Physikalische Chemie

Crystal structure of hydrazinium monofluoride

Abstract

The hydrazinium monofluoride N2H5F crystallizes with orthorhombic symmetry, space group P212121,a=4.592 Å,b=8.217 Å,c=12.341 Å, and 8 formula units. The structure was determined by the permutation method in projection, and by the three-dimensionalPatterson function, refined by Full-Matrix-Least-Squares (R=0.056). The structure consists of N2H5+- and F-ions, bonded with hydrogen bonds N−H ... N and N−H ... F. Each N2H5+ ion is surrounded by four F-ions and two nitrogen atoms of two different N2H5+ ions. Each F ion is connected with four different N2H5+ ions.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literatur

  1. 1.
    P. Glavič undJ. Slivnik, Mh. Chem.98, 1878 (1967).Google Scholar
  2. 2.
    J. Zupan, P. Glavič undM. Drofenik, J. Chem. Physics51, 2382 (1969).CrossRefGoogle Scholar
  3. 3.
    P. Glavič undD. Hadži, Spectrochim. Acta28 A, 1963 (1972).CrossRefGoogle Scholar
  4. 4.
    J. M. Robertson, J. Sci. Instr.20, 175 (1934).CrossRefGoogle Scholar
  5. 5.
    Für die Lösung der Struktur wurden eigene Programme und die CDC 3300 Rechenmaschine des RRC-Ljubljana verwendet.Google Scholar
  6. 6.
    Die Struktur wurde an der University of California (Berkeley) verfeinert. Dazu wurden eine lokale Version des Full-Matrix-Least-Squares-LONG-Programmes, ein modifiziertes FORDAP-Programm (Differenzsynthese) und die CDC 6600 Rechenmaschine verwendet.Google Scholar
  7. 7.
    M. M. Woolfson, Acta Crystallogr.7, 65 (1954).CrossRefGoogle Scholar
  8. 8.
    D. T. Cromer undJ. T. Waber, Acta Crystallogr.18, 104 (1965).CrossRefGoogle Scholar
  9. 9.
    D. W. J. Cruickshank, Computing Methods and the Phase Problem in X-ray Crystal Analysis, Pergamon Press, New York 1961.Google Scholar
  10. 10.
    K. Sakurai undY. Tomiie, Acta Crystallogr.5, 293 (1952).CrossRefGoogle Scholar
  11. 11.
    R. L. Collin undW. N. Lipscomb, Acta Crystallogr.4, 10 (1951).CrossRefGoogle Scholar
  12. 12.
    P. A. Giguère undV. Schomaker, J. Amer. Chem. Soc.65, 2025 (1943).CrossRefGoogle Scholar
  13. 13.
    K. Sakurai undY. Tomiie, Acta Crystallogr.5, 289 (1952).CrossRefGoogle Scholar
  14. 14.
    M. L. Kronberg undD. Harker, J. Chem. Physics10, 309 (1942).CrossRefGoogle Scholar
  15. 15.
    J. Donohue undW. N. Lipscomb, J. Chem. Physics15, 115 (1947).CrossRefGoogle Scholar

Copyright information

© Springer-Verlag 1974

Authors and Affiliations

  • L. Golič
    • 1
  • F. Lazarini
    • 1
  1. 1.Laboratorium für Anorganische Chemie der UniversitätLjubljanaJugoslawien

Personalised recommendations