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Oxidative dearylation of triphenylamine derivatives

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Conclusions

  1. 1.

    Under the action of excess hydrogen peroxide in boiling acetic acid, ortho-substituted derivatives of triphenylamine are converted to the corresponding nitrobenzene derivatives.

  2. 2.

    p-Nitrotriphenylamine and o-nitrodiphenylamine also enter into this reaction.

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 446–447, February, 1967.

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Grib, A.V. Oxidative dearylation of triphenylamine derivatives. Russ Chem Bull 16, 432–434 (1967). https://doi.org/10.1007/BF00912468

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Keywords

  • Hydrogen
  • Acetic
  • Hydrogen Peroxide
  • Acetic Acid
  • Nitrobenzene