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Über Erdalkalimetalloxogallate. VIII Synthese und Aufbau eines neuen Calciumoxogallats: Ca3Ga4O9

Preparation and structure of a new calciumoxogallate:Ca 3 Ga 4 O 9

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Abstract

The hitherto unknown compound Ca3Ga4O9 was prepared and investigated by X-ray single crystal methods. Ca3Ga4O9 has orthorhombic symmetry:a=1435.8;b=1682.5;c=532.1 pm; space group C 2v 11 −Cmm2,Z=6. The tetrahedra network (circles of 4 and 5 GaO4-tetrahedra) and the surrounding of Ca2+ are described and discussed with respect to other oxogallates.

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Schulze, A., Müller-Buschbaum, H. Über Erdalkalimetalloxogallate. VIII Synthese und Aufbau eines neuen Calciumoxogallats: Ca3Ga4O9 . Monatshefte für Chemie 112, 149–156 (1981). https://doi.org/10.1007/BF00911081

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Keywords

  • Calcium
  • Gallium
  • Oxygen
  • Single Crystal
  • X-Ray