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Hydrogenation of α-alkylfurfuryl alcohols over an Ni-ZnO catalyst

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Summary

In the hydrogenation of α-alkylfurfuryl alcohols in the vapor phase over an Ni-ZnO catalyst at 200–250°, reduction of the hydroxy group occurs with formation of 2-alkylfurans; these compounds are converted, partially or completely according to the temperature, into the corresponding aliphatic ketones as a result of the hydrogenolysis of the ring at the C-O bond.

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Literature cited

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    R. Paul, Bull. (5), 4, 846 (1937).

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    J. Pierce and R. Adams, J. Am. Chem. Soc. 47, 1098 (1925).

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    N. I. Shuikin and I. F. Bel'skii, Proc. Acad. Sci. USSR 117, 95 (1957).

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Shuikin, N.I., Bel'skii, I.F. Hydrogenation of α-alkylfurfuryl alcohols over an Ni-ZnO catalyst. Russ Chem Bull 7, 487–488 (1958). https://doi.org/10.1007/BF00910942

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Keywords

  • Hydrogenation
  • Alcohol
  • Ketone
  • Vapor Phase
  • Hydroxy Group