Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Study of ionic association of salts of nitro-compounds in solutions

Communication 1. Association of salts of X gem-dinitroalkanes and trinitromethane in water

  • 22 Accesses

Conclusions

  1. 1.

    The ionic association of organic and inorganic dinitromethane, gem-dinitroethane, and trinitro-methane salts was studied in aqueous solutions at 25°.

  2. 2.

    The values of the limiting equivalent electric conductivity and the dissociation constants of the salts studied were determined, and it was shown that their association in water is negligible, with the exception of the mercury salt of trinitromethane.

  3. 3.

    The values of the limiting equivalent electric conductivity of dinitromethane, gem-dinitroethane, and trinitromethane anions were calculated.

  4. 4.

    The Stokes radii of the ions studied and the interionic distances in the ion pairs were calculated.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    F. Borgardt, A. Seeler, and P. Noble, J. Organ. Chem.,31, 2806 (1966).

  2. 2.

    A. Hantzsch and A. Rinckenberger, Ber.,32, 628 (1899).

  3. 3.

    S. S. Novikov, T. I. Godovikova, and V. A. Tartakovskii, Izv., AN SSSR. Otd. Khim. N., 505 (1960).

  4. 4.

    H. Parker and E. Parker, J. Amer. Chem. Soc.,46, 312 (1924).

  5. 6.

    R. Fuoss and T. Schedlovsky, J. Amer. Chem. Soc.,71, 1496 (1949).

  6. 7.

    H. Dagget, J. Amer. Chem. Soc.,73, 4977 (1951).

  7. 8.

    S. Glasstone, Electrochemistry of Solutions [Russian translation], ONTI, Khimteoretizdat, Leningrad (1936).

  8. 9.

    V. I. Slovetskii, V. A. Tartakovskii, and S. S. Novikov, Izv. AN SSSR. Otd. Khim. N., 1400 (1962).

  9. 10.

    P. Walden, Electrolytes and Solvents [Russian translation], ONTI, Goskhimtekhizdat, lLeningrad (1934).

  10. 11.

    S. S. Novikov, V. I. Slovetskii, S. A. Shevelev, and A. A. Fainzil'berg, Izv. AN SSSR. Otd. Khim. N., 598 (1962).

  11. 12.

    R. Pearson and R. Dillon, J. Amer. Chem. Soc.,75, 2439 (1953).

  12. 13.

    H. Ley and A. Hantzsch, Ber.,39, 3149 (1906).

  13. 14.

    R. Robinson and R. Stokes, Solutions of Electrolytes [Russian translation], IL (1963).

  14. 15.

    C. Parker, H. Emmons, H. Rolewich, and K. Callum, Tetrahedron,17, 79 (1962).

  15. 16.

    E. Nightingale, Jr., J. Phys. Chem.,63, 1381 (1959).

Download references

Author information

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1054–1060, March, 1968.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Slovetskii, V.I., Toshcheva, A.F., Fainzilberg, A.A. et al. Study of ionic association of salts of nitro-compounds in solutions. Russ Chem Bull 17, 1004–1008 (1968). https://doi.org/10.1007/BF00910832

Download citation

Keywords

  • Aqueous Solution
  • Mercury
  • Electric Conductivity
  • Dissociation Constant
  • Ionic Association