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Study of ionic association of salts of nitro-compounds in solutions

Communication 1. Association of salts of X gem-dinitroalkanes and trinitromethane in water

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  1. 1.

    The ionic association of organic and inorganic dinitromethane, gem-dinitroethane, and trinitro-methane salts was studied in aqueous solutions at 25°.

  2. 2.

    The values of the limiting equivalent electric conductivity and the dissociation constants of the salts studied were determined, and it was shown that their association in water is negligible, with the exception of the mercury salt of trinitromethane.

  3. 3.

    The values of the limiting equivalent electric conductivity of dinitromethane, gem-dinitroethane, and trinitromethane anions were calculated.

  4. 4.

    The Stokes radii of the ions studied and the interionic distances in the ion pairs were calculated.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1054–1060, March, 1968.

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Slovetskii, V.I., Toshcheva, A.F., Fainzilberg, A.A. et al. Study of ionic association of salts of nitro-compounds in solutions. Russ Chem Bull 17, 1004–1008 (1968). https://doi.org/10.1007/BF00910832

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  • Aqueous Solution
  • Mercury
  • Electric Conductivity
  • Dissociation Constant
  • Ionic Association