The ionic association of organic and inorganic dinitromethane, gem-dinitroethane, and trinitro-methane salts was studied in aqueous solutions at 25°.
The values of the limiting equivalent electric conductivity and the dissociation constants of the salts studied were determined, and it was shown that their association in water is negligible, with the exception of the mercury salt of trinitromethane.
The values of the limiting equivalent electric conductivity of dinitromethane, gem-dinitroethane, and trinitromethane anions were calculated.
The Stokes radii of the ions studied and the interionic distances in the ion pairs were calculated.
This is a preview of subscription content, log in to check access.
Buy single article
Instant access to the full article PDF.
Price includes VAT for USA
Subscribe to journal
Immediate online access to all issues from 2019. Subscription will auto renew annually.
This is the net price. Taxes to be calculated in checkout.
F. Borgardt, A. Seeler, and P. Noble, J. Organ. Chem.,31, 2806 (1966).
A. Hantzsch and A. Rinckenberger, Ber.,32, 628 (1899).
S. S. Novikov, T. I. Godovikova, and V. A. Tartakovskii, Izv., AN SSSR. Otd. Khim. N., 505 (1960).
H. Parker and E. Parker, J. Amer. Chem. Soc.,46, 312 (1924).
R. Fuoss and T. Schedlovsky, J. Amer. Chem. Soc.,71, 1496 (1949).
H. Dagget, J. Amer. Chem. Soc.,73, 4977 (1951).
S. Glasstone, Electrochemistry of Solutions [Russian translation], ONTI, Khimteoretizdat, Leningrad (1936).
V. I. Slovetskii, V. A. Tartakovskii, and S. S. Novikov, Izv. AN SSSR. Otd. Khim. N., 1400 (1962).
P. Walden, Electrolytes and Solvents [Russian translation], ONTI, Goskhimtekhizdat, lLeningrad (1934).
S. S. Novikov, V. I. Slovetskii, S. A. Shevelev, and A. A. Fainzil'berg, Izv. AN SSSR. Otd. Khim. N., 598 (1962).
R. Pearson and R. Dillon, J. Amer. Chem. Soc.,75, 2439 (1953).
H. Ley and A. Hantzsch, Ber.,39, 3149 (1906).
R. Robinson and R. Stokes, Solutions of Electrolytes [Russian translation], IL (1963).
C. Parker, H. Emmons, H. Rolewich, and K. Callum, Tetrahedron,17, 79 (1962).
E. Nightingale, Jr., J. Phys. Chem.,63, 1381 (1959).
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1054–1060, March, 1968.
About this article
Cite this article
Slovetskii, V.I., Toshcheva, A.F., Fainzilberg, A.A. et al. Study of ionic association of salts of nitro-compounds in solutions. Russ Chem Bull 17, 1004–1008 (1968). https://doi.org/10.1007/BF00910832
- Aqueous Solution
- Electric Conductivity
- Dissociation Constant
- Ionic Association