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β-Dicarbonyl compounds

Communication 9. Reaction of β-dicarbonyl compounds with hydrogen peroxide

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Summary

  1. 1.

    Under the action of hydrogen peroxide 1,3-cyclohexanedione and dimedon undergo oxidative cleavage to glutaric and 3,3-dimethylglutaric acids.

  2. 2.

    The oxidation of 2-oxocylopentanecarboxaldehyde with hydrogen peroxide in neutral and alkaline media leads to the formation of adipic acid. Under the same conditions 2-oxocyclohexanecarboxaldehydes give mixtures of pimelic and cyclopentanecarboxylic acids.

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Literature cited

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Additional information

Continuation of series of papers on the chemistry of 1,3-cyclohexanedione. For Communication 8 see Zhurnal Obshchei Khimii 30, 3658 (1960).

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Vinogradova, L.P., Zav'yalov, S.I. β-Dicarbonyl compounds. Russ Chem Bull 10, 1380–1383 (1961). https://doi.org/10.1007/BF00910114

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Keywords

  • Oxidation
  • Hydrogen
  • Hydrogen Peroxide
  • Alkaline Media
  • Adipic Acid