We have synthesized and characterized epoxyethylphenyldi(trimethylsiloxy)silane, epoxyethyltri(trimethylsiloxy)silane, and methylepoxyethyldi(trimethylsiloxy)silane.
Epoxidation of vinylorganosiloxanes by perbenzoic acid is a second-order reaction; the reaction velocity depends on the polarities and volumes of the substituent radicals at the silicon atom.
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Nozdrina, L.V., Mindlin, Y.I. & Andrianov, K.A. Some laws governing epoxidation of vinylorganosiloxanes. Russ Chem Bull 16, 2022–2024 (1967). https://doi.org/10.1007/BF00909611
- Silicon Atom
- Substituent Radical