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Some laws governing epoxidation of vinylorganosiloxanes

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Conclusions

  1. 1.

    We have synthesized and characterized epoxyethylphenyldi(trimethylsiloxy)silane, epoxyethyltri(trimethylsiloxy)silane, and methylepoxyethyldi(trimethylsiloxy)silane.

  2. 2.

    Epoxidation of vinylorganosiloxanes by perbenzoic acid is a second-order reaction; the reaction velocity depends on the polarities and volumes of the substituent radicals at the silicon atom.

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Literature cited

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2100–2102, September, 1967.

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Nozdrina, L.V., Mindlin, Y.I. & Andrianov, K.A. Some laws governing epoxidation of vinylorganosiloxanes. Russ Chem Bull 16, 2022–2024 (1967). https://doi.org/10.1007/BF00909611

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Keywords

  • Silicon
  • Silane
  • Epoxidation
  • Silicon Atom
  • Substituent Radical